x Flashcards

1
Q

oxidation number of uncombined element

A

0

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2
Q

combined hydrogen oxidation element

A

+1

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3
Q

combined oxygen oxidation element

A

-2

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4
Q

ion of element oxidation element

A

ionic charge

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5
Q

oxidising agent

A

gain of electrons

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6
Q

reducing agent

A

loss of electrons

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7
Q

what are voltaic cells

A
  • electrochemical cell

- converts chemical energy into electrical energy

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8
Q

what do half-cells contain?

A

chemical species present in a redox half- equation

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9
Q

standard electrode potential definition

A

e.m.f of a half- cell connected to a standard hydrogen half-cell under standard conditions of 298K, solution concentrations of 1 moldm-3, and a pressure of 100kPa

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10
Q

the more negative the E value

A

greater the reactivity of a metal in losing electron

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11
Q

the more positive the E value

A
  • greater the reactivity of a non-metal in gaining electrons
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12
Q

what are the charge carriers in the wire

A

electrons

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13
Q

what are the charge carriers in the salt bride

A

ions

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14
Q

most negative system

A
  • greater tendency to be oxidised

- lose electrons

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15
Q

most positive system

A
  • greater tendency to be reduced

- gain electrons

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16
Q

state the limitations of predictions for feasibility based on E values

A
  • reactivity may have a slow rate with high activation energy
  • concentration may not be 1 modm-3, changing the E value