x Flashcards
homogeneous equilibrium definition
all the species in same state or phase
heterogeneous equilibrium definition
species have different state or phase
calculate the equilibrium quantities of 2NO(g) + O₂(g) -> 2NO₂(g)
1.60mol NO(g) and 1.40mol O₂(g) are mixed together in a container with a volume 4.0dm³. At equilibrium, 1.20mol NO₂(g) has formed. Find Kc.
2 mol 1 mol 2 mol 1.60 1.40 0 -1.20 -0.6 +1.20 0.40 0.80 1.20 [NO(g)]= 0.4/4=0.1 moldm⁻³ [O₂(g)]=0.8/4=0.2 moldm⁻³ [NO₂(g)]= 1.2/4=0.3 moldm⁻³ Kc = (0.3)²/(0.1)²X0.2= 45dm³mol⁻¹
write the equation for the mole fraction x(A)
number of moles of A/ total number of moles in gas mixture
what is the sum of mole fractions?
1
partial pressure p(A) equation
mol fraction of A x total pressure P
x(A) x P
what does the sum of partial pressures equal
total pressure
partial pressure for
H₂(g) + I₂(g) ⇄ 2HI(g)
Kp= p(HI)²/ p(H₂)/p(I₂)
what must be ignored in a Kp expression
species other than gases as only gases have partial pressures