Week 4 Day 1 Flashcards
Le chatelier’s principle
can be used to predict the affect of change in conditions on a chemical equilibrium
Keq= [Ceq]c * [Deq]d/[Aeq]a * [Beq]b
Dissociation of water
[H+]=[OH-] = 1.0 x 10-7
acid
molecule that donates a H+
base
molecule that accepts an H+
conjugate base
what is left after an acid has donated a proton
conjugate acid
formed by a base accepting a hydrogen
Henderson-Hasselbalch equation
pH = pKa + log([A-] / [HA])
Used to calculate the pH of a buffer and states the pH of a buffer is equal to the pKa of the weak acid plus the log of the ratio of the concentration of the conjugate base [A-], divided by the concentration of the acid [HA]
buffer
a solution that can resist change in pH upon addition of acidic or basic components
Usually consists of a weak acid and its conjugate base
Normal values:
pH
CO2
HCO3
pH: 7.4 (7.35-7.45)
CO2: 40 mmhg (35-45)
HCO3: 24 mM (20-28)
acute respiratory acidosis
Increased CO2
decreased pH
increased HCO3-
normal BE
chronic respiratory acidosis
increased CO2
close to normal pH
very increased HCO3-
> +2 BE
acute metabolic acidosis
decreased CO2
decreased HCO3- or increased H+
decreased pH
negative <-2 BE
Chronic metabolic acidosis
decreased CO2
decreased HCO3-
about normal pH
negative <-2 BE
Acute respiratory alkalosis
decreased CO2
decreased HCO3-
increased pH
normal BE
chronic respiratory alkalosis
decreased CO2
very decreased HCO3-
about normal pH
negative <-2 BE
acute metabolic alkalosis
increased CO2
increased HCO3-
increased pH
positive >+2 BE
chronic metabolic alkalosis
increased CO2
increased HCO3-
about normal pH
positive >+2 BE
anion gap
Na+ - (Cl- + HCO3-)
high anion gap = addition of acid
normal anion gap = loss of base
HCl
Hydrochloric acid
strong acid
HBR
hydrobromic acid
HI
hydroiotic acid
HNO3
nitric acid
HClO3
chloric acid
HClO4
perchloric acid
H2SO4
sulfuric acid
LiOH
lithium hydroxide
NaOh
sodium hydroxide
KOH
potassium hydroxide
RbOh
rubidium hydroxide
CsOH
cesium hydroxide
Ca(OH)2
calcium hydroxide
Sr(OH)2
strontium hydroxide
Ba(OH)2
barium hydroxide