Unit 2: (d) Esters, fats, and olis Flashcards

1
Q

What are 3 uses of esters?

A

Food flavouring, Perfumes, Solvents.

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2
Q

How are esters made?

A

By joining an alcohol and carboxylic acid.

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3
Q

Making an ester is an example of what kind of reaction?

A

A condensation reaction.

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4
Q

What is the word equation for making an ester?

A

Carboxylic + alcohol -> ester + water

acid

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5
Q

What is the definition of a condensation reaction?

A

When 2 or more small molecules join together to form a larger molecule with the elimination of a smaller molecule e.g. water.

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6
Q

What is the definition of a hydrolysis reaction?

A

The breaking down of a larger molecule into smaller molecules by reaction with water.

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7
Q

Is making an ester a reversible process?

A

Yes.

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8
Q

What catalyst is used to make an ester and why?

A

Sulphuric acid acts as a catalyst as it provides H+ ions.

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9
Q

What is the first part of an esters name taken from?

A

The alcohol used to make it.

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10
Q

What is the second part of an esters name taken from?

A

The acid used to make it.

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11
Q

Ethanoic acid and methanol will react to create what ester?

A

Methyl-ethanoate

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12
Q

What is the reflux apparatus used for in the hydrolysis of an ester?

A

To break down the ester into the salt and alcohol.

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13
Q

What is the distillation apparatus used for in the hydrolysis of an ester?

A

Separate the salt from the alcohol.

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14
Q

What are the salts formed in the hydrolysis of esters used for?

A

Soaps.

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15
Q

What are esters hydrolysed to?

A

Alcohols and carboxylic acids.

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16
Q

What type of molecule are fats and oils?

A

Esters.

17
Q

What do fats and oils do?

A

Provide energy to plants and animals.

18
Q

What is the alcohol present in fats and oils?

A

Glycerol.

19
Q

What is the chemical name for glycerol?

A

Propan-1,2,3-triol.

20
Q

How can fats an oils be classified? Give 3 examples.

A

Fats and oils can be classified according to there origin. Plant, Animal, Marine.

21
Q

Why is glycerol classed as a triol?

A

It contains 3 hydroxyl groups.

22
Q

How many carboxylic acids can each OH group combine with?

A

1.

23
Q

What can fats and oils be described as?

A

Triglycerides.

24
Q

How many moles of glycerol and acids do fats and oils contain?

A

One mole of propan-1,2,3-triol and 3 moles of long chain acids.

25
Q

What are the acids in fats and oils said to be?

A

Long chain fatty acids.

26
Q

Why can the acids in fats and oils be described as long chain?

A

They contain lots of Carbons in a chain.

27
Q

Why can the acids in fats and oils be described as fatty?

A

They come from fats and oils.

28
Q

What is the number of carbons in a long chain fatty acid always?

A

Even.

29
Q

What can fats and oils be hydrolysed to?

A

One mole of glycerol and 3 moles of fatty acids.

30
Q

Why are fats solid at room temperature? (explain fully)

A

They contain carbon to carbon single bonds which means that they are more flexible so;
They pack together closely so;
They have larger Van Der Waals forces so;
They have higher melting and boiling points.

31
Q

Why are oils liquid at room temperature? (explain fully)

A

They contain carbon to carbon double bonds which means that they are not very flexible so;
They cannot pack together closely so;
They have weaker Van Der Waals forces so;
They have lower melting and boiling points.

32
Q

Why are unsaturated oils often reacted with hydrogen?

A

To harden them.

33
Q

What catalyst is used in the hydrogenation of oils?

A

Nickle catalyst.

34
Q

How does adding hydrogen harden the oils?

A

The hydrogen adds across the double bond and turns it into a saturated fat allowing the molecules to pack more tightly together.

35
Q

What is the process of adding hydrogen to unsaturated oils known as?

A

Hardening, Hydrogenation, Addition.