Transition Metal Cmplexes Flashcards

0
Q

If red light absorbed

A

green and blue are transmitted cyan colour

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1
Q

White light is though to be a combination of what colours

A

Primary colours
Red
Green
Blue

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2
Q

Green light absorbed

A

Blue and ted transmitted

Magenta

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3
Q

Blue absorbed

A

Reb and green transmitted

Yellow

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4
Q

Why absorb light

A

Electrons absorb light to move to higer energy levels in d-d transitions
If visible part of spectrum light absorbed is taken away from white light

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5
Q

When ligands surrounding metal ion strong field (cyanide) transitions occur

A

In UV region 200-400nm

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6
Q

Complexed containing weak field ligands (water) likely to absorb

A

Light from visible reign therefore making it coloured

400-700nm

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7
Q

What is a heterozygous catalyst

A

Not in the same state as the reactants

Iron in haver process

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8
Q

Transition metals on surface of active sites form bonds to reactant mols by using

A

Partially filled d orbitals to form intermediate complexes

Weakening the covalent bonds in reactant

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9
Q

What is the oxidation status of a catalyst

A

Variable oxidation states

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10
Q

Describe the process vanadium (V) oxide is used

A

Sulphur dioxide oxidised to sulphur trioxide by vanadium

catalyst reduced to (VI) and then reoxidised to (V)

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