Transition Metal Cmplexes Flashcards
If red light absorbed
green and blue are transmitted cyan colour
White light is though to be a combination of what colours
Primary colours
Red
Green
Blue
Green light absorbed
Blue and ted transmitted
Magenta
Blue absorbed
Reb and green transmitted
Yellow
Why absorb light
Electrons absorb light to move to higer energy levels in d-d transitions
If visible part of spectrum light absorbed is taken away from white light
When ligands surrounding metal ion strong field (cyanide) transitions occur
In UV region 200-400nm
Complexed containing weak field ligands (water) likely to absorb
Light from visible reign therefore making it coloured
400-700nm
What is a heterozygous catalyst
Not in the same state as the reactants
Iron in haver process
Transition metals on surface of active sites form bonds to reactant mols by using
Partially filled d orbitals to form intermediate complexes
Weakening the covalent bonds in reactant
What is the oxidation status of a catalyst
Variable oxidation states
Describe the process vanadium (V) oxide is used
Sulphur dioxide oxidised to sulphur trioxide by vanadium
catalyst reduced to (VI) and then reoxidised to (V)