Reaction Feasibility Flashcards

0
Q

What is the standard entropy

A

Entropy of a substance at a pressure of one atmosphere at 298K in J/MOL

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1
Q

What is the entropy

A

Measure of disorder within a system - larger the entropy the larger disorder

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2
Q

What is the third law of thermodynamics

A

Particles are in perfect order at 0K

As temp increases entropy of solid increases until melt point

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3
Q

Straight line in graph shows a

A

Change of state

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4
Q

What is a feasible Reaction

A

One which takes place of its own accord

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5
Q

What is the second law of thermodynamics

A

For a reaction to be feasible the total entropy for a reaction system and it’s surroundings must be positive

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6
Q

If the standard free energy change is less than 0

A

Will be feasible so products will predominate over the reactants
Equilibrium lie to right and K>1

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7
Q

If the standard energy change is greater than 0

A

Reactants will predominate reaction feasible equilibrium lie to left k<1

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