Reaction Feasibility Flashcards
What is the standard entropy
Entropy of a substance at a pressure of one atmosphere at 298K in J/MOL
What is the entropy
Measure of disorder within a system - larger the entropy the larger disorder
What is the third law of thermodynamics
Particles are in perfect order at 0K
As temp increases entropy of solid increases until melt point
Straight line in graph shows a
Change of state
What is a feasible Reaction
One which takes place of its own accord
What is the second law of thermodynamics
For a reaction to be feasible the total entropy for a reaction system and it’s surroundings must be positive
If the standard free energy change is less than 0
Will be feasible so products will predominate over the reactants
Equilibrium lie to right and K>1
If the standard energy change is greater than 0
Reactants will predominate reaction feasible equilibrium lie to left k<1