Transition elements and quantitative analysis Flashcards
bidentate ligand
a ligand which forms two coordinate bonds with a central metal ion
complex ion
a transition metal ion surrounded by ligands, connected by coordinate bonds
coordinate bond
a covalent bond where the shared pair of electrons come from the same atom
coordination number
the total number of coordinate bonds formed between the central metal ion and ligands
disproportionation
a reaction where the same element is oxidised and reduced
hexdentate ligand
a ligand which forms six coordinate bonds with a central metal ion
ligand
a molecule or ion which can donate a pair of electrons to a central metal ion
ligand substitution
a reaction in which one complex ion is replaced with another ligand
optical isomers
molecules which are non-superimposable mirror images
sterioisomer
species with the same structural formula but a different arrangment of atoms in space
transition element
a d-block element that forms at least one ion with an incomplete d sub-shell - more than one oxidation state, form coloured ions and act as catalysts