Lattice Enthalpy and entropy Flashcards

1
Q
A
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1
Q

entropy (S)

A

a measure of the dispersal of energy in a system - the greater the entropy, the more disorded a system is

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2
Q

enthalpy (H)

A

a value which represents the heat content of a system

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3
Q

free energy change (AG)

A

AG = AH - TAS (a process is spontaneous/feasible when the AG is negative)

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4
Q

enthalpy change of atomisation

A

the enthalpy change when one mole of gaseous atoms is formed from its element in its standard state

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5
Q

enthalpy change of formation

A

enthalpy change when one mole of a compound is formed from its elements

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6
Q

enthalpy change of hydration

A

enthalpy change when one mole of gaseous ions is dissolved in water, forming one mole of aqueous ions

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7
Q

enthalpy change of solution

A

enthalpy change when one mole of a compound is completely dissolved in water under standard conditions

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8
Q

first electron affinity

A

the enthalpy change when one mole of gaseous 1- ions is formed from gaseous atoms

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9
Q

first ionisation energy

A

enthalpy change when one mole of gaseous 1+ ions is formed from gaseous atoms

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10
Q

lattice enthalpy

A

enthalpy change when one mole of a solid ionic lattice is formed from its gaseous ions under standard conditions

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11
Q

s

second electron affinity

A

enthalpy change when one mole of gaseous 2- ions is formed from one mole of gaseous 1- ions

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12
Q

second ionisation energy

A

enthalpy change when one mole of gaseous 2+ ions is formed from one mole of gaseous 1+ ions

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13
Q

spontaneous reaction

A

a reaction which can occur at the specified temperature without a constant input of energy

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