topic 8.4 and 18.2 - strengths of acids/bases and calculations Flashcards
pKa
-log(Ka)
pKb
-log(kb)
pH
-log(H⁺(aq))
14 - pOH
pOH
-log(OH⁻(aq))
14 - pH
Ka
10⁻ᵖᴷᵃ
(H⁺(aq))²/HA
Kb
10⁻ᵖᴷᵇ
(OH⁻(aq))²/b
H⁺
√(Ka x HA)
10⁻ᵖᴴ
Kw/(OH⁻)
OH⁻
√(Kb x b)
10⁻ᵖᴼᴴ
Kw/(H⁺)
Strong acid
Weak acid
Effective proton donor - completely ionises in water (->)
Poor proton donor - partially dissociates in water (⇌)
Strong base
Weak base
Effective proton acceptor - completely ionises (->)
Poor proton acceptor - partially dissociates in water (⇌)
Finding the strength of acid/base using conductivity
More ionisation leads to more ions in the solution so more electricity can be transmitted through a solution.
Stronger acid/base causes a light bulb to shine brighter.
Finding the strength of acid/base using neutralisation
Complete ionisation leads to more exothermic reactions occurring. Stronger acid - more exothermic reaction.
Incomplete ionisation leads to less exothermic reactions taking place. Weaker acid - less exothermic.
Stronger acid causes a more exothermic reaction than a weaker acid.
-57 KJ/mol - standard for neutralisation with a strong acid.
Finding the strength of acid/base using rate of reaction
Stronger acids and bases will have a faster rate of reaction.