Topic 2 Bonding + Structure Flashcards

1
Q

What is Ionic Bonding

A

Between oppositely charged ions. Strong electrostatic attraction

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2
Q

Smaller ionic radius and higher ionic charge have what effect

A

Increases strength of bond

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3
Q

3 Physical properties of ionic compounds

A

High melting point
Non conductor of electricity when solid but conductor when molten or liquid
Brittle

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4
Q

What is Covalent bonding

A

Electrostatic attraction between a shared pair of electrons and the nuclei

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5
Q

Long bond vs short bond strength why

A

short is stronger due to increased electrostatic attraction

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6
Q

London Forces

A

Instantaneous dipole, induced dipole
More electrons means more london forces

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7
Q

Pernament dipole caused by

A

polarity of atoms in molecule

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8
Q

What causes hydrogen bonding

A

slightly positive hydrogen and slightly negative other molecule

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9
Q

branched vs non branched boiling

A

Branched is lower due to worse packing together

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10
Q

Why alcohols have a high boiling point

A

Hydrogen bonding

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11
Q

Trend in boiling point of hydrogen halides

A

HF is very high then increasing from HCL to HI. Increase in London forces (van der waals) outweighs electronegativity difference or length of bond

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12
Q

Metallic Bonding is what

A

Strong electrostatic attraction between metal ions and sea of delocalised electrons

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13
Q

Where are giant lattices present

A

Ionic solids (giant ionic lattices)
Covalently bonded solids (giant covalent lattices)
Solid metals (giant metallic lattices)

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14
Q

Structure of covalently bonded substance

A

Simple molecular

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15
Q

Allotropes of carbon

A

Diamond - Everything has 4 covalent bonds
Graphite - Graphene layers with 3 covalent bonds, London forces between layers
Graphene - Thin sheet 3 covalent

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16
Q

Properties of Metallic Lattices

A

High melting + Boiling
electric conductor
thermal conductor
malleable

17
Q

Properties of ionic lattices

A

High melting
Brittle
bad solid conductor but good molten
soluble

18
Q

Properties of molecular solids

A

Low melting and boiling point (only necessary to overcome intermolecular forces)
Non conductor
generally insoluble if no hydrogen