Topic 1 Atomic Structure and Bonding Flashcards
Atom made up of
Protons, Neutrons, Electrons
Relative mass + charge of proton
1, +1
Relative mass + charge of neutron
1, 0
Relative mass and charge of electon
1/1860 , -1
Atomic Number
Number of Protons
Mass Number
Number of protons+ + neutrons
Isotope
Atoms of the same element with different numbers of neutrons and therefore different mass numbers
Relative Atomic Mass
The mass of an atom of an element relative to the mass of one atom of carbon 12
Relative Molecular Mass
Relative Atomic Masses of everyting in molecule added up
Relative Formula Mass
Relative Atomic Masses of everyting in structure added up
2 uses of mass spectrometry
- Identify unknown compounds
- Find relative abundances of isotopes
What will the mass spectrometry graph for chlorine look like
3 peaks, abundance of isotopes determines height
How to find Relative Molecular Mass of polyatomic molecule, and what to look out for
Last spike, discount very last small peak as that will be Carbon 13 or M+1 peak
How does m/z change if charge is +2
Halves
First Ionisation energy
The energy required to remove 1 mole of electrons from 1 mole of an elements atoms to form 1 mole of 1+ ions under standard condition
3 Factors that affect ionisation energy
Atomic Radius
Nuclear Charge
Electron Shielding
Why ionisation energy increases across period
Increased nuclear charge, decreasing atomic radius with the same electron shielding.
Why does ionisation energy dip at group 3 and group 6
Group 3 is a large dip because outer electron is in a p orbital rather than an s orbital
Group 6 is a dip because one p orbital contains 2 electrons, which repel each other
How do emmision spectra provide evidence for existence of quantum shells
When electrons shift back down from higher energy levels they release energy (flame test). use a spectroscope to see EM radiation released and all same so therefore clear there are levels.
What is an orbital
A reigon within an atom that can hold up to 2 electrons with opposite spins
Shape of a p orbital
Peanut/ Dumbell
Shape of an s orbital
Spherical
Electon configuration of Calcium
[Ar] 4s2
4s vs 3d
4s has a lower energy level until after Ca where 3d is lower and electrons start to fill
Hund’s Rule
Electrons will occupy single shells before pairing
Melting + Boiling Point Across a period
Goes down