tooth coloured restorative materials 1: resin composite and bonding agents Flashcards
lo
what properties are we looking for in a material that can restore teeth
- rebuild teeth
-aesthetic teeth - not wear away
- universal composites
what is definition of composite
- composite is a product with at least 2 distinct phases (matrix and strengthening phase)
- purpose is to combine 2 or more materials to produce one with superior properties
- dental composites contain inorganic filler and an organic binder
what are the advantages of composites
- aesthetics
- conservation of tooth structure
- adhesion to tooth structure( through a bonding system)
- Low thermal conductivity
alternative to amalgam
what are the disadvantages of composites
- technique sensitivity
- polymerisation shrinkage
- marginal leakage
- secondary caries
- postoperatie sensitivity
- decreased wear resistance
how does composite set?
- free radical addition polymerisation
- activation
- chemical - organic amine and organic peroxide
- light - camphorquinone + blue light (450-490nm)
- check light
- initation
- propagation
- termination
which type of polymerisation always result in shrinkage
addition polymerisation
- polymer occupy smaller volume than monomer
why is the bond to dentine poor
dentine is wet and acrylic is hydrophobic
what does poor bond to tooth lead to?
poor retention
staining
sensitivity
secondary cares
what do monomer provide
UDMA AND TEGMA
bis-GMA nad TEGMA
- binds filler particles together
- provides ‘workability’
describe the properties of Bis-GMA monomers
- extremely viscous
- large benzene rings
- lowered by adding TEGDMA
- freely movable
- increases polymer conversion
- increases crosslinking
- increases shrinkage
what happens during light curing
- stresses set up at bonding interface
- stress relieved up to ‘ gel point’
- after gel point composite= unyielding
- stress transferred to tooth
- 2mm depth of cure recommended to minimise stress transfer
what are composite fillers used for
- fillers are placed in dental composites to reduce shrinkage upon curing
- materials such as strontium glass, barium glass, quartz, borosilicate glass, ceramic, silica prepolymerized resin or the like are used
how are fillers classified?
- fillers are classified by material, shape and size
- fillers are irregular or spherical in shape depending on the mode of manufacture
- spherical particles are easier to incorporate into a resin mix and to fill more space leaving less resin
- one size spherical particle occupies a certain space
- adding smaller particles fills the space between the larger particles to take up more space
- less resin remaining and therefore, less shrinkage on curing
what do inorganic fillers do
reduce
- polymerisation shrinkage
-water sorption
- thermal expansion
increase
- compressive/tensile strength
- modulus of elasticity
- abrasion resistance
what is the difference between macro fill,nanofill,nanohybrid?
- macro fill - larger filler particles
- nanofil- filler dispersed
- nandohybrid- combination
what does a coupling agent do
- chemical bond
filler particle - resin Matrix
transfers stresses - organosilane (bifunctional molecule)
-siloxane end bonds to hydroxyl groups on filler - methacrylate end polymerises with resin
what are functions of coupling agents
- improve adherence of resin to filler surfaces
- ## chemically coat filler surfaces and increase strength
what are the disadvantages of silanes?
- quickly age in a bottle and become ineffective
- sensitive to water so the silane filler bond breaks down with moisture
- water absorbed into composites results in hydrolysis of the silence bond and eventual filler loss
what are common silane agents
vinyl triethoxysilane
methacryloxypropyltrimehtlyoxysilane
what is the compressive strength of coupling agents
170-260 MPa
(Enamel 100-360, dentine 250-350)