The gas phase Flashcards
What is the temperature and pressure for STP?
273K (0C) and 1 atm
What is the standard volume for an ideal gas (that would normally be used in the ideal gas law)?
22.4 L
This principle says that at constant temperature and pressure, the volume a gas occupies is proportional to it’s number of moles
Avogadro’s principle
(n/V)=(n/V)
This law says that at constant temperature, volume is inversely proportional to pressure
Boyle’s law
PV=PV
This law says that at constant pressure, temperature and volume are proportional
Charles’s Law
(V/T)=(V/T)
This law says that at constant volume, temperature and pressure are proportional
Gay-Lussac’s Law
(P/T)=(P/T)
This law states that the total pressure of a solution is the sum of the partial pressures of each gas
Dalton’s law of partial pressures
This law says that solubility and pressure are directly related
Henry’s Law
What are the 5 assumptions about gases as given by the kinetic molecular theory?
1) The particles have a negligible volume
2) There is no intermolecular attraction or repulsion
3) The particles undergo constant, random collision
4) Collisions between two particles are elastic
5) For all gases, the kinetic energy is a function of temperature and has nothing to do with the type of gas
What does a Maxwell-Boltzman curve show and how can you use one to make comparisons about particle speeds?
The curve shows a distribution of particle speeds at a given temperature, so you can use it to see which particle has the fastest average velocity. From there, it can be assumed that the gas with the lowest molar mass is moving the fastest
What is the difference between diffusion and effusion?
Diffusion occurs when particles flow from a higher concentration to a lower one
Effusion occurs when particles under pressure flow from one compartment to another via an opening
What is the relationship between vapor pressure and boiling point?
VP and BP are inversely related. The more volatile a liquid is (meaning it has a higher VP) the lower the BP is since most of the molecules are already in the gas phase
The less volatile a liquid is (the lower VP it has) the higher the BP since more of the molecules exist in the liquid phase instead of the gas phase
1 atm= ___ kPa
100