Bonding and chemical reactions Flashcards
How can the polarity of an overall molecule differ from the polarity of the individual bonds?
Depending on geometry, a molecule can be overall non-polar (ex: linear CO2). However, the electronegativites of atoms can cause individual bonds to be polar (ex: O is more electronegative than C, so the C=O is polar)
What are coordinate covalent bonds?
A covalent bond in which the shared electrons originate from the same atom
-Commonly seen in Lewis acid/base run’s because one molecule is the designated donor and the other is the designated acceptor
VSEPR:
Linear
___ regions of electron density
___ bond angle
2 regions
180 degree bond angle
VSEPR:
Trigonal planar
___ regions of electron density
___ bond angle
3 regions
120 degree bond angle
VSEPR:
Tetrahedral
___ regions of electron density
___ bond angle
4 regions
109.5 degree bond angle
VSEPR:
Trigonal bi-pyramidal
___ regions of electron density
___ bond angle
5 regions
90, 120, 180 degree bond angle
VSEPR:
Octahedral
___ regions of electron density
___ bond angle
6 regions
90, 180 degree bond angle
What is the octet rule, and when are there/what are the exceptions?
The octet rule says that every atom likes to have 8 electrons in its valence shell
This can be exceeded by atoms that have d orbitals, as those orbitals can hold more than 8 electrons
-More exceptions than atoms that follow the rules