The Atom Flashcards
compound
is a combination of atoms together to form a new substance
element
is a substance made from only one type of atom. An element cannot be broken down into smaller substances
Democritus
proposed that all matter is made up of smaller, indivisible particles, which they named atomos
atomos
indestructable
john dalton
1700’s/early 1800’s
matter is composed of tiny indivisible particles called atoms
all atoms of the one element are identical but are different from the atoms of other elements
Chemical reactions consist of rearranging atoms in simple whole number ratios
Sir JJ Thompson
1897
discovered the electron using a Crooks Tube
Plum Pudding model
Sir Ernest Rutherford
1911
Gold foil experiment
orbital model
discovered the nucleus
electrons orbit the nucleus
most of the mass of the atom is in the nucleus
nucleus contained positively charged particles (protons)
number of protons are equal to the number of electrons
Sir James Chadwik
1932
discovered the existence of the neutron in the nucleus (electrically neutral particles with a mass similar to that of a proton.
bombarded beryllium with alpha particles and discovered Rutherford’s missing neutral particles
explained the existence of isotopes
atomic mass unit
a.m.u.
mass of a proton
neutrons and protons have the same amu
electron amu
1/1840amu
collective name of the particles in the nucleus
nucleons
n˚ + p+
nucleons are held together by
nuclear glue
Atomic number
the total number of protons that are found in the nucleus of an atom
also represents the total number of electrons orbiting the nucleus in the neutral atom.
represented by Z
Mass number
(A)
the collective sum of the number of protons and neutrons (number of nucleons) that are present in the nucleus of an atom
A = n˚ + p+
nuclear formula
n˚ = A - Z
Isotope
are atoms of an element that have the same number of protons, but differing numbers of neutrons in their nuclei - that is, they have differing numbers of neucleons
Relative atomic mass
(Ar)
Average relative mass amu.
Ar = (A1 x %) + (A2 x %) + (A3 x %)
100 100 100
Niels Bohr
Explained the orbiting of electrons
Planetary model
electrons move around the nucleus in fixed orbits. An electron in a particular orbit has constant energy
an electro can absorb energy and move to a higher energy orbit of larger radius when excited
an excited electron can fall back to its original orbit by emitting energy as radiation
electrons can only exist in certain discrete orbitals
Planetary model energy levels
K orbit = max 2 electrons
L orbit = max 8 electrons
M orbit = max 18 electrons
N orbit = max 32 electrons
energy level
area of probability in which an electron would be found orbiting the nucleus of an atom and that these electrons would have energy typical of that region of probability.
Region of probability orbital classification
s orbital
p orbital
d orbital
f orbital
orbitals
these are areas within an energy level in which electrons are allowcated. The orbitals do vary slightly in energy where the s orbital will have the lowest energy within the level, then the p orbital, then the d orbital followed by the f orbital.
Aufbau principle
the energy structure of a multi electron atom is obtained by filling the orbitals one electron at a time, in order of increasing energy starting with the lowest energy.
4s orbital
has less energy than the 3d orbital and thus it will follow the 3p orbital.
Pauli’s exclusion principle
if electrons are placed close to each other, electrostatic forces of repulsion will be present between them.
determined that electrons have opposite spins, which reduced the force of repulsion
Hunds rule of maximum multiplicity
electrons tend to occupy the orbitals one by one and not pair up.
electron confuguration
1s ^2
orbital amount of electrons in the orbital
GroupI GroupII GroupVI GroupVII GroupVIII
Alkali metals Alkaline metals Chalogens Halogens Noble Gases
Valence electrons
the number of electrons that are found in the highest energy level of an atom
Core Electrons
the electrons found in the lower energy levels beneath the highest (valence) energy level. These electrons will ensure that the lower energy levels are full.