The Atmosphere An Introduction Flashcards
What is mixing ratio?
fraction or proportion of the air made up of a air species
What are the types of unit for mixing ratio?
Fraction / Percentage / Parts per million (106) / billion (109) / trillion (1012)
What is concentration?
amount of an air species per unit volume
What is the unit for air quality concentration?
ug m-3
What will happen to mixing ratio and concentration with a change in temp or pressure (altitude)?
Mixing ratio will remain unchanged
Concentration varies as air readily compressible
What can be used to calculate the concentration of air molecules?
Ideal Gas Law
What do the letters in the Ideal Gas Law equation mean? (pV=nRT)
p= pressure
V= volume
n= number of moles
R= gas constant
T= temperature
What is the equation for the Ideal Gas Law?
pV= nRT
What are the units for pressure in the Ideal Gas Law?
Nm-2
Pascals
What is the unit for volume in the Ideal Gas Law?
m*3
What is the gas constant?
8.314 JK-1 mol-1
What is the unit for temperature in the Ideal Gas Law?
K
What is the average air pressure at sea level?
1.013 bar
What unit for pressure will be used on weather maps?
Millibars (mb)
What is 1 bar equal to? (pressure)
105 pascal
105 Nm-2
How many Pa is 1 atmosphere equivalent to?
101325 Pa
How many psi is 1 bar?
14.5 Pound per square inch
How many Torr is 1 atmosphere equivalent to?
760
What is the technical term for heat exchange for most environmental processes?
Enthalpy (J)
What is heat capacity?
how much energy needed to raise temp of ice or water by 1K
What is the heat capacity of ice?
2.108 JK-1g-1
What is the heat capacity of liquid water?
4.182 JK-1g-1
What is the heat capacity of water vapour?
1.996 JK-1g-1
What is the Enthalpy of Melting for water ice?
334 J g-1
What is the Enthalpy of Vaporisation for liquid water?
2230 J g-1
How is the atmosphere divided?
Into layers by altitude (variation in temp with height)
What are the characteristics of the troposphere?
10-15 km high
90% atmospheric mass
Temp decrease as go up
What happens when you get to 10-12 km in atmopshere?
change to stratosphere so temp starts to increase
Why does temp increase in the stratosphere?
Ozone layer found here which absorbs short wave radiation
What is the troposphere made up on? (most to least abundant)
Nitrogen
Oxygen
CO2
H2O
Hydrocarbons
CH4
VOC (volatile organic compounds)
CO
N2O
H2
O3 (ozone)
NO2
OH
O
What happens as you go down the table for the composition of the troposhere?
Less abundant but more reactive
What affects the level of O3 and hydrocarbons?
Reactions involving OH moderated by NOx
What is an example of a short lived atmospheric air species?
OH - few seconds, maybe 1m travelled
Little concern
What is an example of a moderate residence time air species?
NOx- 1 day, 10km
Can be controlled with city projects
What is an example of a long residence time air species?
CFCs- 100yr, global
Requires global action