Test 3: Free Energy Flashcards

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1
Q

Gibbs free energy

A

the total energy released or absorbed in a physical or chemical process.

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2
Q

Gibbs free energy is represented by

A

^G (triangle symbol)

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3
Q

Where ^G is negative, the overall process is __(2)

A

exergonic and spontaneous

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4
Q

Where ^G is positive, the overall process is__(2)

A

endergonic and nonspantanious

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5
Q

A spontaneous reaction is one that

A

continues to occur without any assistance once it has begun.

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6
Q

Any process which requires a constant addition of energy to maintain it is a __process.

A

nonspontaneous

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7
Q

The relationship (factor) between enthalpy, entropy, and free energy

A

^G = ^H - T^S / gibbs free energy= enthalpy - temperature(kelvins)*entropy

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8
Q

at high temperatures we expect ^G to be __, and at low temperatures it should be __.

A

positive; negative

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9
Q

at high temperatures the __value is more important and at low temperatures the __ value is more important.

A

entropic; enthalpy

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10
Q

Energy of Activation

A

spontaneous processes may not occur because the process includes a high energy transition state or intermediate.

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11
Q

The smaller the activation energy the

A

faster the reaction takes place

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12
Q

Before reactants can become products (or spontaneous reactions can occur) they must have enough energy to get over the

A

activation energy or energy of activation

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