Test 3: Free Energy Flashcards
Gibbs free energy
the total energy released or absorbed in a physical or chemical process.
Gibbs free energy is represented by
^G (triangle symbol)
Where ^G is negative, the overall process is __(2)
exergonic and spontaneous
Where ^G is positive, the overall process is__(2)
endergonic and nonspantanious
A spontaneous reaction is one that
continues to occur without any assistance once it has begun.
Any process which requires a constant addition of energy to maintain it is a __process.
nonspontaneous
The relationship (factor/equation) between enthalpy, entropy, and free energy
^G = ^H - T^S / gibbs free energy= enthalpy - temperature(kelvins)*entropy
at high temperatures we expect ^G to be __, and at low temperatures it should be __.
positive; negative
at high temperatures the __value is more important and at low temperatures the __ value is more important.
entropic; enthalpy
Energy of Activation
high energy transition state which must be reached for a spontaneous reaction to occur
The smaller the activation energy the
faster the reaction takes place
Before reactants can become products (or spontaneous reactions can occur) they must have enough energy to get over the
activation energy or energy of activation
What is the difference between exothermic and exergonic?
Exothermic is the release of heat energy (^H), exergonic is the Gibbs total energy released (^G).