Test 2: Covalent bonds & Lewis Dot Structure Flashcards
Resonance Structure
two different valid Lewis dot structures with slightly different electron distribution
Ionic Compounds are nearly always composed of
metals bound to nonmetals.
Lewis dot structure shows
a simple representation of the valence electrons which surround an element
When elements come together to form bonds they share
as many electrons as needed for each side to have a full electronic shell
Some compounds share more than just two pairs of electrons, but the maximum that can be shared is
6 electrons (or 3 pairs)
Steps for writing simple and complex covalent molecules
1 - Count the total number of valence electrons available. This is the sum of the valence electrons in each of the atoms bonding. If the structure is that of an ion, then remove or add a number of electrons equal to the ion charge.
2 - Arrange the atoms in order of connectivity (unless otherwise noted or if it is hydrogen, the FIRST atom listed is the central atom).
3 - Connect the central atom with a single bond to each exterior atom (two shared electrons).
4 - Distribute the remaining electrons like so: A - Add electrons to each exterior atom so they each have a total of 8 (2 if hydrogen).B - Add any remaining electrons to the interior atom.
5 - Evaluate your structure to ensure that all atoms have a full shell. If they do not, share moreelectrons by forming double and/or triple bonds by bringing in electrons from exterior atoms.(Repeat this step until all atoms have a full shell)
VSEPR
is the model we use to predict molecular shape
The basis of Valence Shell Electron Pair Repulsion theory is the understanding that
like charges repel one another.
Because like charges repel one another, multiple electron sets in a covalent molecule will arrange themselves in
a 3-dimensional space to be as far apart from one another as possible while still connected to the central atom.
the shape of simple covalent compounds is determined by
electron sets around a central atom
What qualifies as one electron set?
a lone pair, a single bond, a double bond, or a triple bond (3)
Why do we consider a double bond to be only one electron set even though there are 4 electrons in it?
a double bond, of necessity, must occupy the same (or similar) space as the single bond
electronic geometry of a molecule
the geometric arrangement in space of the electrons surrounding the central atom
geometric shape of two electron sets
Linear; 180º angle
geometric shape of three electron sets
trigonal planar; “a triangle in the same plane”; 120 º angle.