Test 2: Covalent bonds & Lewis Dot Structure Flashcards
Resonance Structure
two different valid Lewis dot structures with slightly different electron distribution
Ionic Compounds are nearly always composed of
metals bound to nonmetals.
Lewis dot structure shows
a simple representation of the valence electrons which surround an element
When elements come together to form bonds they share
as many electrons as needed for each side to have a full electronic shell
Some compounds share more than just two pairs of electrons, but the maximum that can be shared is
6 electrons (or 3 pairs)
Steps for writing simple and complex covalent molecules
1 - Count the total number of valence electrons available. This is the sum of the valence electrons in each of the atoms bonding. If the structure is that of an ion, then remove or add a number of electrons equal to the ion charge.
2 - Arrange the atoms in order of connectivity (unless otherwise noted or if it is hydrogen, the FIRST atom listed is the central atom).
3 - Connect the central atom with a single bond to each exterior atom (two shared electrons).
4 - Distribute the remaining electrons like so: A - Add electrons to each exterior atom so they each have a total of 8 (2 if hydrogen).B - Add any remaining electrons to the interior atom.
5 - Evaluate your structure to ensure that all atoms have a full shell. If they do not, share moreelectrons by forming double and/or triple bonds by bringing in electrons from exterior atoms.(Repeat this step until all atoms have a full shell)
VSEPR
is the model we use to predict molecular shape
The basis of Valence Shell Electron Pair Repulsion theory is the understanding that
like charges repel one another.
Because like charges repel one another, multiple electron sets in a covalent molecule will arrange themselves in
a 3-dimensional space to be as far apart from one another as possible while still connected to the central atom.
the shape of simple covalent compounds is determined by
electron sets around a central atom
What qualifies as one electron set?
a lone pair, a single bond, a double bond, or a triple bond (3)
Why do we consider a double bond to be only one electron set even though there are 4 electrons in it?
a double bond, of necessity, must occupy the same (or similar) space as the single bond
electronic geometry of a molecule
the geometric arrangement in space of the electrons surrounding the central atom
geometric shape of two electron sets
Linear; 180º angle
geometric shape of three electron sets
trigonal planar; “a triangle in the same plane”; 120 º angle.
geometric shape of four electron sets
tetrahedral, or four sided structure, 109.5º angle
What is used to demonstrate a 3D structure?
standard wedge-and-dash notation to solve this problem. The wedge is a bond coming out of the screen towards you and a dash is a bond going into the screen away from you
molecular geometry tells us
the geometric arrangement of the atoms connected with the central atom.
any structure with no lone pairs of electrons has the same
molecular and electronic geometry
A molecule with two electron sets is always
linear.
Depending on the number of atoms attached to it, a molecule with three electron sets is either
trigonal planar or bent
four electron set determining factors
the central atom can be attached to four atoms, to three atoms and one lone pair, or to two atoms and two lone pairs
three electron set determining factors
either the central atom can be attached to three atoms, or to one lone pair and two atoms.
Depending on the number of atoms attached to it, a molecules shape with four electron sets is
tetrahedral, trigonal pyramidal, or bent.
Properties of molecular compounds
Covalent, smallest components are always neutral, usually composed of nonmetal-nonmetal, low melting and boiling point (which means a gas at room temperature) **do not usually conduct electricity if it is not a metal.
The smallest possible unit of a covalent compound is a(an)
molecule
Properties of an ionic compound
conducts electricity when dissolved in water or is melted, composed of a metal-nonmetal