stoich Flashcards

1
Q

percentage yield

A

what you produce experimentally, compared to what was theoretically possible

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2
Q

theoretical yield

A

quantity of product expected to be produced if everything goes perfectly

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3
Q

experimental yield

A

the quantity of product actually produced

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4
Q

percentage yield equation

A

experimental/theoretical x 100%

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5
Q

limiting reagent

A

reactant that limits the quantity of product formed

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6
Q

excess reagent

A

reactant that still has some quantity remaining once the reaction is done

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7
Q

stoichiometry

A

the study of relationship between quantities of reactants and products involved in a chemical reaction

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8
Q

what is the relationship in stoichiometry?

A

molar coefficients of the balanced chemical reaction

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9
Q

mole ratio

A

“stoichiometric ratio”; given by the coefficients of the BCR

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10
Q

Gravimetric stoich solves for…

A

a chemical’s mass

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11
Q

general idea of gravimetric stoich

A
  1. given mass –> moles
  2. connect given moles –> required moles
  3. required moles –> mass
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12
Q

pH curve

A

graphical representation of the progression of an acid-base titration

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13
Q

how is the pH curve obtained?

A

performing a titration of one reactant into a sample flask of the other reactant

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14
Q

if the tip of the burette is perpendicular, then..

A

the tip is closed

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15
Q

if the tip of the burette is parallel, then..

A

the tip is open

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16
Q

what is the burette estimated to compared to what it’s calibrated to

A

estimated to a hundredth, calibrated to a tenth of a mL

17
Q

parts of pH curve when a strong acid is titrated into a strong base

A
  1. OH- only in sample
  2. H3O+ being added
  3. small quantity of H3O+ being added results in dramatic decrease in pH
  4. excess H3O+ (OH- is neutralized)
18
Q

endpoint

A

(y-coordinate) pH @ which the acid and base neutralize

19
Q

appropriate indicators in a titration

A

an indicator with a pH=7 will be a midpoint colour
- bromothymol blue
- phenol red

20
Q

equivalence point

A

(x-coordinate) volume of titrant required to perfectly neutralize sample

21
Q

parts of a pH curve when strong base is titrated into a strong acid

A
  1. excess H30+
  2. equivalence point ( pH increases dramatically as more OH- is added)
  3. excess OH-
22
Q

solution stoich equation

A

c=n/v

23
Q

what does solution stoich solve for

A

volume and concentration

24
Q

what does gas stoich solve for

A

volume

25
Q

gas stoich equation

A

PV=nRT

26
Q

R constant

A

8.314

27
Q

STP

A

101.325 kPa
0C

28
Q

SATP

A

100kPa
25C

29
Q

titration

A

used to determine the concentration of a solution when the concentration of one solution is known and the volume of both solutions is known

30
Q

how can the concentration of an unknown solution be determined (reference to titration)

A

-pH curve
-multi-trial titration

31
Q

multi-trial titration

A

titrant is added to the sample, but the titration is stopped when the endpoint is reached

32
Q

how to determine the volume of titrant required to enutralize the sample

A

Vf - Vi

33
Q

why are multiple trials done in multi-tiral titrations

A
  • improve precision/reliability of results
  • eliminate outlying trials
34
Q

how are trials selected from multi-trial titrations

A

3 trials within +/- 0.20 mL

35
Q

titration data table title

A

titration os xxxx mL (xxx mol/L) sample with (xxx mol/L) titrant