diversity of matter and chemical bonding cont. Flashcards

1
Q

INTRAMOLECULAR BOND

A

covalent bond; bonds within the molecule

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2
Q

INTERMOLECULAR FORCES

A

forces of attraction between molecules
- London Dispersion Forces (LDF)
- Dipole-Dipole Forces (DD)
- Hydrogen Bonding (H-Bond)

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3
Q

Which is strong?
Intermolecular forces
Intramolecular forces

A

Intramolecular forces (Covalent bonds)

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4
Q

London Dispersion Forces (LDF)

A

Special type of vanderwaals force; molecules feel attraction because protons of one feel attraction to electrons of another and vice versa.

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5
Q

How to calculate LDF

A
  • add up atomic # of each atom in moelvule
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6
Q

What does low and high LDF mean?

A

low LDF: low magnitude
high LDF: high magnitude

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7
Q

what molecules have LDF?

A

all molecules, polar or non-polar

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8
Q

Dipole-Dipole Forces (DD)

A

the dipole of one polar molecule aligns with dipoles of neighbouring molecules in 3-D
- Slight- is attracted to the slightly+ of another dipoled

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9
Q

Hydrogen Bonding (HB)

A

strongest of the intermolecular forces

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10
Q

Is HB a DD?

A

yes; special type where a H nucleus is simultaneously attracted to the electron of its intramolecular bond, and a lone electron pair on an adjacent molecule

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11
Q

what qualifies as an HB?

A

H atom directly bonded to N, O , F

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12
Q

Best way to determine presence of intramolecular forces

A
  • create a 3-D image of the molecule
  • create a checklist
    LDF:
    DD:
    HB:
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13
Q

Kinetic Molecular Theory

A
  • All matter is made up of tiny particles
  • These particles are in constant motion
  • As these particles are in motion, they do interact with each other
  • The particles exhibit attractive forces over short distances (intramolecular forces)
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14
Q

Solid

A
  • only vibrational motion
  • flexion within bond length
  • Restricted particles movement
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15
Q

Liquid

A
  • vibrational and rotational motion
  • lightly separated
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16
Q

Gas

A
  • translational motion
  • highest energy particles
17
Q

Order the states of matter from lowest to highest in IMF

A

Gas
Liquid
Solid (holds particles together)

18
Q

order states from lowest to highest in Ek

A

Gas
liquid
solid

19
Q

what happens to IMF when changing from solid to liquid

A

partially overcome IMF

20
Q

what happens to IMF when changing liquid to gas

A

completely overcome IMF

21
Q

properties when condensing

A
  • particles slow down
  • interactions inc.
  • IMF develop
22
Q

properties when freezing

A
  • stronger IMF develop
23
Q

273.15°C

A

absolute zero; all substances are solid

24
Q

molecules with low MP/BP

A

low IMF
low amount of energy needed to overcome

25
Q

molecules with high MP/BP

A

high IMF

26
Q

Solubility statement

A

like dissolves like

27
Q

polar solvents dissolve….

A

polar solutes

28
Q

non-polar solvents dissolve…

A

non-polar solutes

29
Q

are hydrocarbons polar or non-polar

A

all hydrocarbons are non-polaris CO

30
Q

is CO2 soluble in water>

A

no
-water molecules are too attracted
-keep CO2 out, can’t fit in