Spectroscopy Flashcards
Spectroscopy
Study of electromagnetic radiation and its interaction with matter
Light
Composed of photons which have particle-like and wave - like properties
Wavelength
Distance between 2 identical positions on wave
Frequency
Number of crests passing a particular point per second
Amplitude
Distance between resting position and the max displacement
Electromagnetic wave
Has a magnetic and electric component, it interacts with electrons
Energy of uv radiation
Similar to chemical bonding and caused by movement of electrons
Absorption of uv radiation
Absorbed at a particular wavelength corresponding to a particular electronic transition
Monochromator
Has a slit to select a particular wavelength
Pathlength
Thickness of cell
Beer - lambert law
Describes light absorption
Transmittance
Concentrated solution has a low transmission and vice verse
Intensity
Proportional to number of photons
Factors affecting absorption
Solution length and concentration
Molar absorptivity
Specific, depends on chemical nature of compound and is quoted at max wavelength