Equilibrium Flashcards

1
Q

Dynamic equilibrium

A

State where rates of forward and reverse reactions are equal and concentration of reactants and products remain constant

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2
Q

Deuterium labeling in ammonia synthesis

A

Proves ammonia is constantly being formed and consumed

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3
Q

Equilibrium constant ( kc) values

A

Refers to a direction and stoichiometry for a reaction

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4
Q

Electrolyte

A

Dissociates in water into ions

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5
Q

Strong electrolytes

A

Acids and bases that completely ionize

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6
Q

Weak electrolytes

A

Acids and bases that partially ionize

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7
Q

Hydrated proton

A

Hydronium ion

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8
Q

Water auto-ionisation

A

Pure water weakly conducts electricity

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9
Q

Le chatelier’s principle

A

When a stress is applied to a system in dynamic equilibrium, the equilibrium adjusts to minimize the effect of the stress

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10
Q

Henry’s law

A

Amount of a gas in a solution is proportional to its partial pressure above the solution

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11
Q

Homogenous equilibrium

A

Everything is in the same phase

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12
Q

Heterogenous equilibrium

A

Things are in more than one phase

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13
Q

Effect of temperature on kc

A

In exothermic rxn, when temp increases, value of Kc decreases

In endothermic rxn, when temp increases, value of Kc increases

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14
Q

Partial pressure

A

Mole fraction x total pressure

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15
Q

Conditions of haber process

A

400-450degC, 200 atm, iron catalyst w KOH promoter

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16
Q

Conditions of contact process

A

400-450degC, 1-2 atm, V2O5 catalyst

17
Q

Conditions of manufacture of ethanol

A

300degC, 60-70 atm, phosphoric(V) acid catalyst with a solid SiO2 coat