Solutions Flashcards

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0
Q

What does a solution consist of?

A

A solute dissolved in a solvent

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1
Q

What is the term for a homogenous mixture of substances that form a single phase?

A

Solution

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2
Q

How do the solute and solvent molecule interact?

A

Through solvation/ dissolution, known as hydration when water is the solvent, the solvent molecules form a cage-like structure around the solute. It occurs when the attractive forces between solvent and solute are stronger than those between the solute particles.

Like dissolves like!

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3
Q

Solubility

A

The ratio or maximum solute that can be dissolved in a solvent at a given temperature.

(g solute)/ (100 g solvent)

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4
Q

What is the solution when the maximum amount of solute has been added?

A

Saturated

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5
Q

Which salts are water soluble?

A

All salts of alkali metals, ammonium ions (NH^4+), bromides, chlorides, and iodides (except Ag+, Pb^2+, and Hg^2+), sulfates (SO4^2-) (except Ca^2+, Sr^2+, Ba^2+, and Pb^2+).

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6
Q

What are insoluble in water?

A

All metal oxides (except Alkali, CaO, SrO, and BaO), hydroxides (except Alkali, Ca^2+, Sr^2+, and Ba^2+), carbonates, phosphates, sulfides, and sulfates (except Alkali and ammonium) are insoluble.

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7
Q

Aqueous Solution

A

Water is the solvent.

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8
Q

Ion

A

A particle (single or polyatomic) with charge.

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9
Q

Why do permanganate and chromate make good oxidizing agents?

A

They each have an inordinately hight oxidation number, making them more likely to gain electrons to reduce the oxidation number.

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10
Q

Electrolytes

A

Solutes that dissociate in solvent to form a solution that can conduct electricity, producing a larger effect on Colligative properties than would be expected for the concentration.

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11
Q

Concentration

A

Ratio of solute to solvent

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12
Q

Percent composition by mass

A

(mass of solute/ mass of solution) 100

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13
Q

Mole Fraction

A

moles of compound/ total moles in system

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14
Q

Molarity

A

moles of solute/ L of solution

For dilute solution, the volume of solution is approximately equal to volume of solvent.

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15
Q

Molality

A

moles of solute/ kg of solvent

At 25°C for dilute aqueous solutions, molality approximately equals molality, because water has a density of 1 kg/L.

16
Q

Normality

A

gram equivalent of solute weight/ L of solution

Involves concentration of reactive species and it is reaction dependent.

17
Q

Equation used to determine a dilution

A

C1V1 = C2V2

18
Q

Ion Product

A

I.P. = [A^n+]^m [B^m-]^n

19
Q

Solubility Product Constant

A

Ksp = I.P. In saturated solution

It represents an equilibrium at saturation.
I.P. > Ksp, precipitation occurs

x^2, 4x^3, and 27x^4 for MX, MX2, and MX3, respectively

20
Q

What is occurring when the molar solubility of a salt decreases when another salt, with a common ion, is in the solution.

A

The Common Ion Effect is an example of Le Châtelier’s Principle.

21
Q

Solution Equilibrium

A

The point where the rate of dissociation equals the rate of precipitation, even with the addition of more solute.

22
Q

Molar Solubility

A

Molar amount of solute dissolved in 1 L of solvent until saturation.