Acids and Bases Flashcards

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0
Q

Who described bases as hydroxide ion producers in aqueous solutions?

A

Svante Arrhenius also defined acids as proton producers in aqueous solutions.

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1
Q

What is litmus paper?

A

It is a chemical indicator that turns red in acidic solutions and blue in basic solutions. It changes color as the comprised chemicals dissociate. Indicators signal the end point during titration.

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2
Q

How do Johannes Brønsted and Thomas Lowry define acids and bases?

A

The Brønsted-Lowry definition describes acids as proton donors and bases as proton acceptors.

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3
Q

Conjugate Acids and Bases

A

Appearing on opposite sides of the chemical equation, conjugate acids and bases are the protonated/ deprotonated forms of a chemical.

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4
Q

What is the most inclusive definition of acids and bases?

A

The Lewis definition describes acids as electron-pair acceptors and bases as electron-pair donors.

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5
Q

pH

A

pH = -log[H+]

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6
Q

pOH

A

pOH = -log[OH-]

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7
Q

Water Dissociation Constant

A

Kw = [H+][OH-]

At 25°C, Kw = 10^-14 and pKw = 14

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8
Q

Acid Dissociation Constant

A

The degree of acid dissociation, where a weak acid has a smaller Ka.

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9
Q

PI

A

The isoelectric point is where there is no electrical charge.

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10
Q

Strong Acid

A

Acids that completely dissociate in aqueous solutions, like HClO4, HNO3, HI, H2SO4, and HCl.

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11
Q

Diprotic Base

A

Two moles of protons accepted per mole of base.

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12
Q

Which reaction between an acid and base form a water and salt?

A

Neutralization reactions form water and salt. These tend to be between a strong acid and strong base or a weak acid and strong base. Weak bases tend to not be hydroxides.

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13
Q

Amphoteric

A

A chemical that can either be an acid or a base depending on its chemical environment.

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14
Q

Titration

A

A procedure used to determine an unknown concentration of known volume by adding a solution of known concentration and known volume to the point of molar equivalency as shown by an indicator.

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15
Q

Half-Equivalence Point

A

Point of titration when exactly half the molar equivalence of reactant has been consumed by the titration, where the pK equals the pH.

16
Q

Equivalence Point

A

It occurs when an equimolar amount of titrant has been added.

17
Q

Buffets

A

Mixture of a weak acid an it’s salt that resists changes in pH.

18
Q

Henderson-Hasselbalch Equation

A

pH = pKa + log ([conjugate base]/[weak acid])

pOH = pKb + log ([conjugate acid]/[weak base])