Resonance Flashcards

1
Q

Evidence for resonance

A

All bond angles are equal
All C-C bond lengths are equal
All C-H bond lengths are equal
C-C bond length is between those of double and single bonds

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2
Q

Resonance and equilibrium

A

Resonance does not mean equilibrium

Averaging effect rather than rapid alternation

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3
Q

Conjugated

A

Having a mixture of single and multiple bonds

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4
Q

Aromaticity

A

The delocalisation of 6 𝛑 electrons around a ring
e.g. Benzene
2/3 of 100 million are aromatic
Special stability - less reactive

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5
Q

Aromatic Heterocycles

A

Ring is broken by N atom

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6
Q

Rules of resonance

A
  1. are imaginary
  2. Are less stable than the resonance hybrids
  3. differ only in their position of their 𝛑 or non-bonding electrons
  4. need not be equivalent
  5. obey the normal rules of valency
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