Reactions Flashcards
1
Q
Hydrolysis
A
cleavage of a σ bond by H2O
2
Q
Addition
A
2 reactants – 1 product
cleavage of 𝛑 bonds
3
Q
Elimination
A
1 reactant – 2 product
4
Q
substitution
A
2 reactants exchange parts – 2 products
5
Q
Rearrangement
A
1 reactant– isomer
6
Q
Sn2
A
substitution, nucleophilic, bimolecular
7
Q
Sn1
A
substitution, nucleophilic, unimolecular
stepwise mechanism
8
Q
Nucleophobic addition
A
𝛑 bond
aldehydes and ketones
9
Q
Electrophobic addition
A
σ electrons
Alkenes
10
Q
Nucleophilic acyl substitution
A
Aldehydes and ketones– stable tetrahedral
Carboxylic acid and derivatives– does not– addition-elimination mechanism
11
Q
Tautomerism
A
most common rearrangement
moves 1 proton and pi bond
enrol–etones and aldehydes
12
Q
Radical
A
Abstraction
radical addition
