Redox and Electrode potentials Flashcards

1
Q

what are the rules of balancing half equations

A

write down the species before an after reaction
balance any atoms apart from oxygen and hydrogen
if needed balance any oxygens with H2O and balance hydrogens with H+ ions
Balance charges with electrons

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2
Q

describe properties of transition elements

A

oxidise and reduce other substance
have variable oxidation states
have different colours depending on oxidation states

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2
Q

name two oxidising agents

A

potassium dichromate and acidified permanganate

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3
Q

how would you conduct an iodine- sodium thiosulfate solution

A

,measure out volume of KIO3 (25cm3)
add excess acidified potassium iodide solution to KIo3 solution
add solution into conical flask
add sodium thiosulfate into conical flask and look for pale yellow colour
as the colour change is diifiult to see add 2cm3 of starch
deep colour remains if iodine is still present in starch
when the blue colour disappears the iodine has been used up

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4
Q

what electrode is used if we have an inert but electrically conductive electrode

A

platinum

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5
Q

electrons always flow from a ____ reactive metal to a _____ reactive metal

A

more less

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6
Q

what is the salt bridge made from in an electrochemical cell

A

KNO3

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7
Q

if the electrode potential is negative then the half cell will undergo

A

oxidation

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8
Q

if the electrode is has a positive value then the half cell will undergo

A

reduction
NO PRoblem

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9
Q

which equation is flipped when constructing overall cll equations

A

oxidation (most negative)

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10
Q

how would you set top a standard hydrogen electrode

A

add H2
at 298K ans 100kpa

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11
Q

how do you calculate cell potential

A

reduced-oxidised

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12
Q

what are the advantages and disadvantages of furl cells

A

+ more efficient
hydrogen powered
more kinetic energy
don’t need recharge
only waste product is water
- highly flammable
expensive to transport
energy is required to make hydrogen in first place

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12
Q

all feasible reaction shave a positive what

A

e cell value

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