Periodicity Flashcards

1
Q

who credited the periodic table today and how was it structured

A

ordered it by atomic mass but left gaps where elements didn’t fit Newlands theory
elements now grouped in terms of similar chemical properties

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2
Q

how is the modern periodic table grouped

A

by proton number
same group has similar properties
periods are rows and columns are group
elements in same period have same number of electron numbers

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3
Q

how is the periodic table grouped into s,p,d and f block

A

left side s block
middle is d block
right id b block
bottom is f block

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4
Q

what is ionisation energy

A

minimum amount of energy required to remove 1 mole of electrons from 1 mole of atoms in the gaseous state

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5
Q

how does shielding affect ionisation energy

A

the more electron shells between positive nucleus and negative electron being removed the less energy is required

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6
Q

how does nuclear charge affect ionisation energy

A

the more protons in the nucleus the bigger the attraction between nucleus and outer electrons, more energy to remove the electron

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7
Q

ionisation requires energy therefore they are always

A

endothermic and have a positive value

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8
Q

ionisation energy _____as we go down a group

A

decreases

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9
Q

why does ionisation energy decrease as we go down a group

A

atomic radius increases
attractive force is weaker
energy required decreases
shielding increases

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10
Q

ionisation energy ___ as we go across a period

A

increases

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11
Q

why does ionisation energy increase as we go across a period

A

increasing number of protons
nuclear attraction increases
shielding is similar
more energy required to remove outermost electron

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12
Q

how does aluminium provide evidence for sub shells

A

the outermost electron sits in a higher energy sub-shell slightly higher energy sub shell which is further from the nucleus

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13
Q

how is sulphur evidence for electron repulsion in an orbital

A

phosphorus and sulfur both have outer electrons in the 3p orbital so shielding is the same
removing electron from sulfur involves taking it from an orbital with two electrons
electrons repel each other so less energy needed remove electron from orbital with two electrons than one

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14
Q

what is successive ionisation

A

when more than one electron is removed from the same atom

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15
Q

what are two examples of giant covalent structures

A

graphite and diamond

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16
Q

describe the structure of graphite and its features

A

each carbon bonded three times, 4th electron is delocalised
layers slide as weak forces between layers
delocalised electrons allow conduction of electricity
strong covalent bonds mean high melting point
insoluble

17
Q

describe the structure and function of diamond and its properties

A

each carbon bonded four times
tightly packed so can conduct heat
high melting point due to strong covalent bonds
doesn’t conduct electricity
insoluble

18
Q

what substance is diamond similar to

A

silicon

19
Q

what bonding is present in metals

A

giant metallic lattice

20
Q

what is the structure and properties of graphene

A

1 layer of graphite
made up of hexagonal carbon rings
delocalised, free moving electrons which strengthen covalent bonds and allow conduction of electricity
transparent and light

21
Q

what is the use of graphene

A

aircraft shells
super computers
smart phone screens

22
Q

describe metallic bonding and how this gives metals their property

A

positive metal ions amongst sea of delocalised electrons
electrostatic attraction between positive metal ions and negative delocalised electrons
the more electrons the higher the melting point
good thermal conductors
high melting points
good electrical conductors
insoluble as metallic bonds are strong

23
Q

how does melting point change across a period

A

increase as metals have increasing positive charge
increasing number of delocalised electrons
smaller ionic radius so stronger metallic bond

24
Q
A