amines, amino acids and chirality Flashcards

1
Q

give the structure of a quaternary amine

A
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2
Q

give the structure of a tertiary amine

A
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3
Q

give the structure of a secondary amine

A
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4
Q

give the structure of a primary amine

A
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5
Q

what is an amine

A

is derived from ammonia and all contain a nitrogen atom where hydrogen are replaced with an organic group

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6
Q

what type of amine is an aromatic amine

A

primary

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7
Q

non aromatic amines are known as what

A

aliphatic

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8
Q

what do amines act as and why

A

act as a base due to the lone pair on nitrogen which is able to attract electrons via dative covalent bonding

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9
Q

what effects the strength of the base

A

density, the higher the electron density the more readily available the electrons are

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10
Q

how are aliphatic amines made and what is the by product

A

reacting a halogenalkane with excess ammonia
ammonium chloride

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11
Q

how do you make aromatic amines

A

reducing nitro compounds such as nitrobenzene
step1: heat under reflux with conc. HCl to form a salt
step2: salt produced is reacted with an alkali such as NaOH to produce an aromatic amine

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12
Q

what are amides

A

derivatives of carboxylic acids and have the functional group CONH2

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13
Q

draw the general structure of an amino acid

A
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14
Q

amino acids are amphoteric what does this mean

A

they have acidic and basic properties

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15
Q

amino acids are chiral what does this mean

A

it has four different groups attached to a central carbon atom

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16
Q

amino acids to react with acids and alkalis to form what

A

salts

17
Q

_____ react with the carboxylic group in an amino acid to form a conjugate base and water

A

alkalis

18
Q

_____ react with the amino group to form a conjugate acid

A

acids

19
Q

amino acids react with alcohols to form what
give the catalyst

A

esters
sulfuric acid

20
Q

what is optical isomerism

A

mirror images of each other, have a chiral carbon atom, forms enantiomers

21
Q

what does non- superimposable mean

A

do not cross over

22
Q
A