Reactivity series Flashcards
The order of reactivity can be determined by
Adding acid to different metals and observing the rate of reaction
Water can be used to test the relative reactivity of metals. However, many metals are too low in the reactivity series to react with water
A metal will displace another metal from its oxide that is
lower in the reactivity series
A metal will also displace another metal from its salt that is
lower in the reactivity series
Order of reactivity series
Potassium Sodium Lithium Calcium Magnesium Aluminium Zinc Iron Copper Silver Gold
Iron rusts when
water and oxygen are present
Barrier methods
Rusting may be prevented by stopping the water and oxygen getting to the iron with a barrier of grease, oil, paint or plastic.
Galvanising
(coating in zinc) also prevents water and oxygen getting to the iron, but with galvanising even if the barrier is broken the more reactive zinc corrodes before the less reactive iron. During the process, the zinc loses electrons to form zinc ions.
Sacrificial protection
Zinc blocks are attached to iron boat hulls and underground pipelines. Zinc is more reactive than iron, so oxygen in the air reacts with the zinc to form a layer of zinc oxide instead of the iron.
Oxidiation
Oxidation is the loss of electrons.
Another definition of oxidation is the gain of oxygen. For example if carbon combines with oxygen to form carbon dioxide, the carbon is being oxidised.
Reduction
Reduction is the gain of electrons
Another definition of reduction is the loss of oxygen. For example when aluminium oxide is broken down to produce aluminium and oxygen, the aluminium is being reduced.
Redox
A reaction involving oxidation and reduction
Oxidising agent
A substance that gives oxygen or removes electrons (it is itself reduced).
Reducing agent
A substance that takes oxygen or gives electrons (it is itself oxidised).
Metals which are above hydrogen in the reactivity series will react with dilute hydrochloric or sulfuric acid to produce
A salt and hydrogen - displacement reaction
Metals which are above hydrogen in the reactivity series will react with dilute hydrochloric or sulfuric acid- observations
there is a rapid fizzing
the gas pops with a lighted splint, showing the gas is hydrogen.
the reaction mixture becomes warm as heat is produced (exothermic).
the magnesium disappears to leave a colourless solution of magnesium chloride.