Reactivity 3.4 Flashcards
What happens when Alkenes react with Bromine water?
Bromine water changes from brown to clear.
Define heterolytic fission, specific to nucleophilic substitution
Formation of a carbocation and a negative ion, due to carbon losing its shared electron.
Define nucleophile
Reactants with a non-bonding electron pair that is attracted to a positive carbon cation
Define SN2 reactions
SN2 reactions involve heterolytic fission and
nucleophilic substitution with mainly primary
halogenoalkanes.
Define SN1 reactions
SN1 reactions involve heterolytic fission and nucleophilic substitution with mainly tertiary halogenoalkanes.
Does rate increase or decrease down halogen group for SN1
Increase
Does the number of alkyl groups affect the reaction rate for SN2 reactions
Yes, the less alkyl groups there are, the higher the rate of reaction due to steric hindrance.
Does the number of alkyl groups affect the reaction rate for SN1 reactions
Yes, the more alkyl groups there are, the higher the rate of reaction due to steric hindrance.
What is a lewis acid
A substance that accepts an electron pair
What is a lewis base
A substance that accepts an electron pair