Reaction Pathways Flashcards

1
Q

Alkene to alkane

A

H2 and Nickel Catalyst at 423K.

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2
Q

Alkene to haloalkanes

A

Add HX. (X being the halide)

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3
Q

Alkene to alcohols

A

H20(g) and H3PO4.

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4
Q

Alcohols to ketone

A

[O], K2Cr2O7, H2SO4.

Reflux.

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5
Q

Alcohols to carboxylic acid

A

2[O] and H2SO4 / K2Cr2O7

Reflux

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6
Q

Alcohols to aldehyde

A

[O] and H2SO4/ K2Cr2O7

Distil

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7
Q

Alkanes to alkene

A

Alkanes –> Haloalkanes –> Alcohols –> Alkene

  1. Halogen + UV
  2. NaOH + Reflux
  3. Concentrated H2SO4 and reflux
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8
Q

Alkanes to haloalkanes

A

Halogen + UV.

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9
Q

Alcohols to haloalkanes

A

Na and H2SO4.

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10
Q

Alkene to primary alcohol

A

Hydration

H3PO4/H20.

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11
Q

Primary alcohol to alkene

A

H2SO4

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12
Q

Alkene to Haloalkane

A

HX

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13
Q

Haloalkane to nitrile

A

NaCN

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14
Q

Nitrile to amine

A

H2/Ni catalyst.

reduction

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15
Q

Nitrile to carboxylic acid

A

H20/ HCl hydrolysis

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16
Q

Haloalkane to amine

A

NH3/ ethanol

17
Q

Haloalkane to primary alcohol

18
Q

Primary alcohol to haloalkane

A

NaX / H2SO4

19
Q

Primary alcohol to aldehyde

A

K2Cr2O7 / H2SO4

oxidation

20
Q

Aldehyde to primary alcohol

A

NaBH4/ H20 reduction

21
Q

Aldehyde to hydroxynitrile

A

NaCN /H+

nucleophilic addiiton

22
Q

Aldehyde to carboxylic acid

A

K2Cr2O7 / H2SO4

oxidation

23
Q

Primary alcohol to ester

A

Carboxylic acid/ H2SO4 esterification.

24
Q

Carboxylic acid to acyl chloride

25
Acyl chloride to carboxylic acid
H20
26
Ester to COO-Na+ and alcohol
NaOH alkaline hydrolysis
27
Ester to carboxylic acid
Dilute acid hydrolysis
28
carboxylic acid to ester
Esterification | Alcohol/ H2SO4
29
Acyl chloride to primary amide
NH3
30
Acyl chloride to secondary amide
Primary amine.
31
Benzene to nitrobenzene
HNO3 / H2SO4 | nitration
32
Benzene to methylbenzene
alkylation | CH3CL / AlCl3
33
Benzene to acylbenzene
CH3COCl / AlCl3
34
Benzene to chlorobenzene
Cl2 /AlCL3 | chlorination
35
Benzene to bromobenzene
Br2 / FeBr3 | bromination
36
Nitrobenzene to phenyl amine
Sn/ HCl | reduction
37
phenyl amine to tri bromo phenyl amine
Br2