Chapter 4 - Acids and redox Flashcards

1
Q

What is a Bronsted- Lowry Acids

A

They are defined to be proton donors.

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2
Q

What is a Bronsted-Lowry Base

A

They are defined to the proton acceptors

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3
Q

Give 3 examples of strong acids

A
Sulfuric acid (H2SO4)
Hydrochloric acid (HCl)
Nitric acid (HNO3)
Because they are all inorganic acids (or minerals)
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4
Q

Give an example of a weak acid

A
Ethanoic acid (CH3COOH)
Just carboxylic acids in general because they are organic acids.
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5
Q

What is the difference between an alkali and a base

A

An alkali is any soluble base.

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6
Q

3 examples of strong alkalis

A

NaOH
KOH
Ca(OH)2

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7
Q

1 example of a weak acid

A

NH4OH

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8
Q

acid + alkali –>

A

salt and water

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9
Q

acid + carbonate –>

A

salt + water + carbon dioxide

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10
Q

Ionic equation for neutralisation

A

H+(aq) + OH-(aq) –> H20 (l)

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11
Q

Explain sulfuric acid’s strength

A

It has 2 hydrogen atoms, but it is only strong for one of them. So it fully dissociates with 1, and then partially dissociates in the other.
H2SO4(aq) –> H+(aq) + HSO4-(aq)
HSO4-(aq) H+(aq) + SO4 2- (aq)

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12
Q

ionic equation for acid and oxides

A

2H+ + O2- –> H20

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13
Q

ionic equation for acid and carbonates

A

2H+ + CO3 2- –> H2O + CO2

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14
Q

ionic equation for when water mixes with hydrogen

A

H+(aq) + H2O(l) –> H3O+(aq)
This happens by a dative covalent bond because the oxygen had 2 lone pairs, one of which it now shares with this third hydrogen.
The new compound is called hydroxonium.

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15
Q

What is titration

A

A technique used to accurately measure the volume of an unknown solution that reacts exactly with another known solution.

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16
Q

What can titrations be used for

A

finding the concentration of a solution
identification of unknown chemicals
finding the purity of a substance

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17
Q

Explain diprotic molecule

A

It is a molecule that has 2 hydrogens. Immediately, this is the stronger acid because it has more hydrogen ions to release and carry the charge.

18
Q

As a solution is diluted, what happens to its current flow

A

If a solution is diluted, the concentration of H+ ions decreases. If there is less ions to carry the charge, the electrical conductivity will decrease.

19
Q

Why does a stronger acid have a higher electrical conductivity?

A

A stronger acid can ionise fully and release more ions per unit of volume of solution to carry the charge through the electrolyte.

20
Q

Rule for halogens

A

They are usually -1.

But they are positive with oxygen and fluorine

21
Q

Rule for hydrogen with metals

A

-1 oxidation number

22
Q

Rule for hydrogen with non- metals

A

+1 oxidation number

23
Q

Rule for oxygen

A

Usually -2

But -1 is peroxide (H2O2)

24
Q

Rule for fluorine

25
How to calculate percentage uncertainty
uncertainty/ capacity * 100%
26
What is the % uncertainty on a 100cm3 volumetric flask
+- 0.20cm3
27
What is the % uncertainty on a 250cm3 volumetric flask
+- 0.30cm3
28
Effect on titre if the pipette has an air bubble
creates a smaller titre because there is actually less volume
29
Effect on the titre if the burette reading are taken from the top, rather than the bottom of the meniscus
Wouldn't be affected because the change in volume would still be the same.
30
when do you multiply the number by 2 when calculating the % uncertainty
if you have used that object twice
31
Uncertainty of a 10cm3 pipette
+- 0.04 cm3
32
Uncertainty of a 25cm3 pipette
+- 0.06cm3
33
Uncertainty of a 50cm3 pipette
+- 0.10cm3 (0.05 * 2 because its read twice)
34
oxidation numbers: | reduction
decrease in oxidation number
35
oxidation numbers: | oxidation
increase in oxidation numbers
36
H in metal hydrides
-1
37
O in peroxide (H2O2)
-1
38
O is bonded to F
+2
39
nitrite
no2 +3
40
nitrate
no3 +5