Chapter 7 - Periodicity Flashcards
atomic number
(left to right)
it is arranged in order of increasing atomic numbers
every element has atoms with 1 extra electron (than the one before)
groups
each element in a group has the same number of outer-shell electrons and similar properties
periods and periodicity
the no. of period = number of highest energy electron shell in an element’s atom.
groups 1 and 2 are what block
s block
groups 3 - 12 are what block
d block
groups 15 - 18 are what block
p block
the bottom block is called
f block
what are group 1 called
alkali metals
what are group 2 called
alkaline earth metals
what are group 3-12 called
transition elements
what are group 15 called
pnictogens
what are group 16 called
chalogens
what are group 17 called
halogens
what are group 18 called
noble gases
what is first ionisation energy
the energy required to remove 1 electron from each atom in 1 mole of gaseous atoms of an element to form 1 mole of gaseous +1 ions.
what is ionisation energy
how easily an atom loses electrons to form positive ions
factors that affect the ionisation energies?
nuclear charge (the higher the no. of protons, the higher the attraction between the nucleus and the outer electrons) atomic radius (increased distance to get to furthest shell, decreasing the attraction) electron shielding (electrons repel each other, so its called the shielding effect, which reduces the attraction)
what is the second ionisation energy
the energy required to remove 1 electron from each ion in 1 mole of gaseous 1+ ions of an element to form 1 mole of 2+ gaseous ions.
give an example of ionisation energy using helium
He has 2 protons and 2 electrons. It loses the first electron and then the other electron actually gets a higher attraction from the proton. This means that the 2nd ionisation energy will be greater than the first.
Explain a graph that shows ionisation energies
the ionisation energy from one shell to another changes dramatically.
Trends of ionisation energy in a period
- a general increase in first ionisation energy across a period.
- a sharp decrease in F.I.E from the end of a period and the beginning of another.
Explain the trend down a group
- atomic radius increases
- more inner shells so the amount of shielding increases
- nuclear attraction decreases.
- F.I.E decreases.
Explain the trend across a period
- Nuclear charge increase
- Same shell
- Nuclear attraction increases
- Atomic radius decreases
- F.I.E increases
Sub-shell trends
Across a group, the ionisation energy will increase till a sub-shell is filled up, and then decrease slightly, then build up again.