reaction overviews Flashcards
1
Q
alkoxymercuration-demercuration
A
- anti addition of H and OH
- Markovnikov
2
Q
BH3-THF
NaOH, H2O, H2O2
A
- anti-Markovnikov
- syn addition of H and OH
3
Q
Cl2, Br2, I2
A
- anti addition of X, X
4
Q
Cl2, Br2, I2
H2O
A
- anti addition of X, OH
- OH goes on more highly substituted carbon
5
Q
H2
Pt, Pd, Ni
A
- syn addition of H
6
Q
CH2I2
Zn, CuCl
A
triangle
7
Q
CHBr3, Cl, I
NaOH, H2O
A
triangle with 2 X attached
8
Q
mCPBA
CH2Cl2
A
epoxide addition
9
Q
mCPBA
H3O+
A
- anti OH addition
10
Q
OsO4, H2O2
A
- syn OH addition
11
Q
KMnO4, warm, concentrated
A
carboxylic acids
12
Q
O3, -78 C, S(CH3)2
A
aldehydes
