Rates Of Reactions (chpt. 16) Flashcards

1
Q

Rate of reaction

A

The change in concentration of any one reactant or product per unit of time

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2
Q

Instantaneous rate of reaction

A

The rate of reaction at any one particular time during the reaction

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3
Q

Catalyst

A

A substance that alters the rate of a chemical reaction but is not consumed in the reaction

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4
Q

Enzyme

A

An enzymes is a a substance that is produced by a living cell and acts as a biological catalyst

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5
Q

Homogeneous catalysis

A

Catalysis in which both the reactants and the catalyst are in the same phase, i.e. there is no boundary between the reactants and the catalyst

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6
Q

Heterogenous catalysis

A

Both the reactants and the catalyst are in different phases

E.g. Oxidation of methane using a platinum catalyst

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7
Q

Autocatalysis

A

One of the products of the reaction acts as a catalyst for the reaction

↳ starts slowly but speeds up as the catalyst product forms

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8
Q

Catalytic converter

A

A device in the exhaust system of a motor vehicle which contains catalysts to convert pollutants in the exhaust gases to less harmful substances

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9
Q

Catalyst poison

A

A substance that makes a catalyst inactive

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10
Q

Effective collision

A

One that results in the formation of products

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11
Q

Activation energy

A

The minimum energy that colliding particles must have for a reaction to occur

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12
Q

Explain why increasing temperature has a significant effect on the rate of reaction

A

More effective collisions

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13
Q

State and explain three factors that have an effect on the rate of a chemical reaction

A

Concentration → more particles therefore more collisions
Particle size → greater surface area means more particles exposed for collisions
Nature of the reactants → ionic fast, covalent slow
Presence of a catalyst → lowers the activation energy

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14
Q

Give the name and symbol of one metallic element used as a catalyst in the catalytic converter of a car

A

Platinum Pt

Palladium Pd

Rhodium Rh

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15
Q

How can a catalyst lower the activation energy of a reaction

A

Provides alternative pathway / mechanism for the reaction

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16
Q

Surface adsorption theory - key points

A

• reactants adsorbed onto surface of catalyst
• strong bonds form between reactants
• products diffuse away from surface

17
Q

Suggest a reason why chemical reactions are generally slow when the reactants are kept together in the solid state

A

Very little motion of particles in solids

Few collisions

18
Q

Why are reactions with ionic bonds generally fast at room temperature?

A

Ionic bonds broken already

19
Q

Why are reactions with covalent bonds generally slow at room temperature?

A

Bonds must be broken before reaction can take place