Chemical Bonding (chpt. 5) Flashcards

1
Q

Compound

A

A substance made up of two or more different elements combined together chemically

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2
Q

Octet rule

A

When bonding occurs, atoms tend to reach an electron arrangement with 8 electrons in the outer shell

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3
Q

Exceptions to octet rule

A

Transition metals
Elements near helium - full shell of 2

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4
Q

Ion

A

Charged atom or group of atoms

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5
Q

Ionic bond

A

The force of attraction between oppositely charged ions in a compound
Ionic bonds are always formed by the complete transfer of electrons from one atom to another

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6
Q

Sodium chloride crystal structure

A

Ionic crystal lattice
Forms crystals because positive ions attract negative ions in all directions
DRAW
Na +
Cl -

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7
Q

Properties of transition metals

A
  • Variable valency
  • Forms coloured compounds
  • Used as catalysts
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8
Q

Transition metal

A

One that forms at least one ion with a partially filled d sublevel

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9
Q

Molecule

A

A group of atoms joined together
Smallest particle of an element or compound that can exist independently

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10
Q

Electronegativity

A

The relative attraction that an atom in a molecule has for the shared pair of electrons in a covalent bond

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11
Q

Electronegativity

A

The relative attraction that an atom in a molecule has for the shared pair of electrons in a covalent bond

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12
Q

Inter molecular bonding

A

Forces of attraction that exist between molecules
E.g. van der waals, dipole-dipole, hydrogen bonding

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13
Q

Van der waals

A

Weak attractive forces between molecules resulting from the formation of temporary dipoles. Only force of attraction between non-polar molecules

Weakest
Temporary dipole-dipole
Non-polar molecules
Higher boiling point as number of electrons increases

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14
Q

Dipole-dipole

A

Forces of attraction between negative pole of one polar molecule and the positive pole of another polar molecule
Stronger than van der waal
Polar-covalent molecules

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15
Q

Hydrogen bonding

A

NOF
3 most electronegative elements
Strongest
Hydrogen is slightly positive and attracted to slightly negative other element
High boiling points

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16
Q

Intramolecular bonding

A

Bonding that takes place within a molecule
E.g. covalent bonding

17
Q

Valency

A

The number of atoms of hydrogen or any other monovalent element with which each atom of the element combines

18
Q

Sigma bond

A

The head on overlap of two orbitals
Strong as there is more overlap

19
Q

Pi bond

A

Formed by the sideways overlap of p orbitals

20
Q

Double bond

A

Consists of one sigma and one pi bond

21
Q

Triple bond

A

Consists of one sigma and two pi bonds

22
Q

Properties of ionic substances

A
  • Network of ions in crystal
  • Usually hard and brittle
  • High melting and boiling points
  • Usually solid at room temperature
  • Conduct electricity in molten state or when dissolved in water
23
Q

Properties of covalent substances

A
  • Contain individual molecules
  • Usually soft
  • Low melting and boiling points
  • Usually liquids, gases or soft solids at room temp
  • Do not conduct electricity