Rates of reaction (6.1) (M) Flashcards
How do you calculate rate of reaction?
quantity of reactant used or product formed / time taken
How do you calculate mean rate of reaction?
quantity of reactant used or product formed / time taken - for the whole reaction
Note: the line is likely to be extended once the reaction is complete (disclude this from the calculation)
How do you calculate the rate of reaction at a specific point?
Draw a tangent and calculate gradient
5 needed
Which factors increase the rate of reaction?
By increasing:
- the concentrations of reactants in solution
- the pressure of reacting gases
- the surface area of solid reactants
- the temperature
- the presence of catalysts
What does collision theory state?
Chemical reactions can occur only when reacting particles collide with each other and with sufficient energy.
What is activation energy?
The minimum amount of energy that particles must have to react
How does increasing the concentration of reactants in solution, the pressure of reacting gases, and the surface area of solid reactants increase the rate of reaction?
increases the frequency of collisions (more of particle is exposed for SA for same mass, more particles per unit volume to collide with for pressure/conc) and so increases the rate of reaction
How does increased temperature increase the rate of reaction?
The particles move faster.
This increases the frequency of collisions and makes the collisions more energetic (collisions have energy greater than activation energy in some mark schemes)
What do catalysts do in chemical reaction?
Catalysts change the rate of chemical reactions but are not used up during the reaction (reduce activation energy)
Why can’t we use the same catalyst for every reaction?
Different reactions need different catalysts
What type of catalyst are enzymes?
Biological catalysts
What is the role of enzymes?
Enzymes act as catalysts in biological systems
How do catalysts increase the rate of reaction?
By providing a different pathway for the reaction that has a lower activation energy
Draw a reaction profile for a catalysed reaction
As below
4 marker
In a reaction between calcium carbonate and hydrochloric acid, how does the rate of reaction change as the reaction progresses?
acid particles used up
so concentration decreases
so less frequent collisions
so rate decreases