Rates of reaction Flashcards

1
Q

what are the units of rate?

A

mol dm-3 s-1

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2
Q

what is zero order?

A

the concentration of the reactant has no effect on the rate

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3
Q

what is first order?

A

the rate depends on the concentration to the power of 1

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4
Q

what is second order?

A

the rate depends on the concentration to the power of 2

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5
Q

where does the overall order come from?

A

the sum of the orders of the reactants

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6
Q

what are 3 ways of continuous monitoring?

A

gas collection, mass loss, colour change

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7
Q

what does a colorimeter measure?

A

light absorption

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8
Q

what is the gradient equal to?

A

the rate

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9
Q

what is the half life?

A

the time taken for half of the reactant to be used up

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10
Q

what is the name for a constant half life?

A

exponential decay

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11
Q

how do you determine the rate constant?

A

calculate from the rate by drawing a large tangent.

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12
Q

which order has a constant half life?

A

first

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13
Q

what is an example of a clock reaction?

A

Iodine and starch colour change

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14
Q

what is necessary for a reaction to take place?

A

right orientation and enough energy

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15
Q

what is the slowest step?

A

the rate determining step

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16
Q

what are haloalkanes hydrolysed with?

A

hot aqueous alkali

17
Q

how do you find the overall reaction?

A

the sum of the reaction steps

18
Q

what happens to rate when temperature increases?

A

it increases

19
Q

what is the change in rate mainly determined by?

A

activation energy

20
Q

what is the Arrhenius equation?

A

the exponential relationship between the rate constant and temperature

21
Q

what type of graph is produced from the Arrhenius equation?

A

straight line downwards