Rates Of Reaction Flashcards

1
Q

Rate of reaction

A

Change in concentration of a reactant(or product) per unit time

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2
Q

Average rate

A

The amount of product/ period of time

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3
Q

Activation energy

A

Minimum energy colliding particles must have in order to react

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4
Q

Catalyst

A

A substance that alters the rate of a chemical reaction but is not used up at the end of the reaction

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5
Q

Factors affecting rate of reaction

A
  1. Temperature
  2. Concentration
  3. particle size
  4. nature of reactants
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6
Q

Temperatures affect on reaction rate

A

Th higher the Temperature the larger the proportion of particles that have activation energy

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7
Q

Particle size affect on reaction rate

A

The smaller the particles- the faster the rate of reaction due to larger surface area.

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8
Q

Nature of reactants

A

Ionic compounds react very quickly/ covalent compounds react slowly

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9
Q

Auto catalyst

A

One of the products of the reaction catalyses the reaction

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10
Q

Why does the rate of chemical reaction generally decrease with time?

A

Concentration decreases and reactants are used up

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11
Q

Give three conditions necessary for a dust explosion to occur

A

Dryness
Above certain concentration
Enclosed space

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12
Q

Effective Collision

A

Reaches activation energy and results in product formation

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13
Q

Homogenous catalyst

A

Catalyst and reactants are in Same phase

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14
Q

Heterogeneous catalysts

A

Catalyst and reactants in different phases

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15
Q

Surface absorption

A

Reactants are absorbed onto the surface of the catalyst and the products released when formed thus freeing active site again

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16
Q

Intermediate compound formation

A

Catalyst forms unstable intermediate with reactants and decomposes readily releasing the products

17
Q

Explain how the type of bonding in the reactants influences the rate of a chemical reaction in aqueous solutions

A

Ionic compounds react quickly in solution as dissociated ions only need to collide

18
Q

How could you reduce the rate of reaction that takes place in solution?

A

Lowering the temperature or lowering the concentration

19
Q

two observations of the oxidation of methanol using platinum wire

A

Wire glows/ odour of methanol

20
Q

Absorption

A

The attachment of liquid or gaseous molecules to a solid surface

21
Q

Explain how absorption affects the rate of oxidation

A

Bonds weekend and lower activation energy/ more effective collisions

22
Q

Explain how a catalyst poison like sulfur interferes with a catalyst

A

Active site occupied/blocked by poison

23
Q

How does temperature speed up reaction?

A

The higher the temperature the larger the proportion of particles that have activation energy.

24
Q

How does concentration speed up a rate of a reaction?

A

Closer molecules means more collisions per unit time

25
Q

How does a catalyst speed up a rate of reaction?

A

Lowers activation energy/more effective collisions / forms activated complex

26
Q

Name two of the metals used as catalysts in catalytic converters

A

Platinum

Rhodium

27
Q

Name a substance that could poison the catalysts of the catalytic converter.

A

Sulfur compounds/ lead compounds

28
Q

Two products in oxidation of methanol using platinum wire as a catalyst

A

Methanol and hydrogen gas

29
Q

Heat of reaction formula

A

Heat/no. Of moles