Organic Flashcards

1
Q

4 bonding 0 lone pairs

A

Tetrahedral

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2
Q

3 bonding 1 lone pair

A

Pyramidal

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3
Q

3 bonding 0 lone pairs

A

Trigonal

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4
Q

2 bonding 2 lone pairs

A

Angular

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5
Q

2 bonding 0 lone pairs

A

Linear

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6
Q

Linear angle

A

180

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7
Q

Angular angle

A
H20= 204.5 
H2S= 102
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8
Q

Trigonal angle

A

120

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9
Q

Pyramidal angle

A

107

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10
Q

Tetrahedral angle

A

109.5

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11
Q

Effect of adding a little tetraethyllead to an equimolar mixture of methane and chlorine

A

Reaction rate increases / tetraethyllead acts as a catalyst

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12
Q

Primary alcohol

A

One carbon attached to hyroxyl carbon

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13
Q

Why is boiling point of propanol higher than that of butane?

A

Propanol is polar/ butane is non-polar /has weaker intermolecular forces

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14
Q

Why is the boiling point of ethanoic acid higher than that of prop-1-ol?

A

Ethanoic acid has more hydrogen bonding / 2 polar groups

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15
Q

Organic product of reaction of propanol with acidified dilute KMnO4

A

Propanoic acid

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16
Q

How to demonstrate that ethene readily undergoes an addition reaction with bromine water

A

Bubble combine ethene with bromine water / red /de colorised

17
Q

Delocalised

A

Shared between more than two atoms

18
Q

How many electrons in benzene molecule are delocalised

A

6

19
Q

How many electrons in benzene molecule are involved in sigma bonds

A

12

20
Q

Molecular formula of eugonol

A

C10H12O2

21
Q

Name a spectroscopic technique that could help confirm identity of a sample of eugonol

A

Mass spectrometry/ IR

22
Q

Infrared spectrometry

A

Molecules absorb of different frequencies

23
Q

a use that propanoic acid, benzoic acid and the salts of these acids have in common

A

Suits pharmaceutical industry / labour costs high

24
Q

What was observed in flaks as water was dropped onto CAC2 (prepare ethyne)

A

Reaction turns milky/ bubbling

25
Q

Explain why the first few test tubes of gas collected were discarded (prepare ethyne)

A

Contain air/ impure

26
Q

Collection of ethen

A

Side ways test tube/ glass wool and ethanol inside / aluminium oxide

27
Q

Safety precautions during experiment

A

Keep long hair tied back- avoid burns/ wear mask- avoid contact with chemicals

28
Q

Compare observations made in two tests on ethyne and ethene

A

Ethyne- flame smokey/ ethene- clean

29
Q

Reagent used to test gases for unsaturation

A

Bromine

30
Q

Describe how to chemically test sample for unsaturation

A

Bromine/ acidified pottasium manganate/ decolorises if unsaturated

31
Q

Describe a chemical test to confirm ethanol can be very easily oxidised

A

Fehling’s solution/ heat/ blue solution reacts to give red

32
Q

Name a laboratory technique to purify impure benzoic acid

A

Recrystallisation

33
Q

Method to measure melting point of benzoic acid

A

Sample in test tube in melting point block/ heat slowly/ record melting temp

34
Q

Appearance of phenylmethanol at room temp

A

Pale yellow/colourless

35
Q

Purify benzoin acid

A

Sample in melting point tube on melting point block/ heat slowly / note temp when melting occurs