rate of reaction Flashcards
what is collision theory
chemical reaction occur when reactants collide successfully for a collision to be successful, the reactant particles must collide with correct orientation which is greater than or equal too activation energy of reactant
what effects collision theory
- temperature
- pressure
- surface area
- addition of a catalyst
how does increasing temperature affect collision theory
increases the rate of reaction due to more kinetic energy at higher temperatures
how does increasing concentration and pressure affect collision theory
increasing concentration/ pressure increases rate of reaction. this is because there is an increase of reactant particles in the same volume therefore larger chance of collisions
how does increasing surface area affect collision theory
increases rate of reactions as it exposes more particles to the surface which allows them to have a higher chance of collisions
how does the addition of a catalyst affect collision theory
increases rate of reaction
the equation for calculating rate of reaction
rate = change in concentration / time
what does the boltzmann energy distribution curve
at a given temperature, not all the particles in a sample have the same energy.
what effect does the catalyst have on a reaction
changes the activation energy
define a homogeneous catalyst
same physical state as the reactants. takes active part in the reaction and are then regenerated as the reaction proceeds
define a heterogenous catalyst
different physical state as reactants. provides a surface for reactant particles to absorb to, which holds them in place to react. the product then desorb from the surface
how to measure rate of reaction by gas collection method
rate of reaction = volume/time
what is the iodine clock used for
to compare reactions under different conditions. it involves setting up reactions with known concentration and time is recorded
describe the method of an iodine clock
- add these to a conical flask
- KI
- sodium thiosulfate
- starch solution - add 5cm of hydrogen peroxide to the mixture and start stopwatch
- stop timer when it turns blue black
- repeat using different conc of hydrogen peroxide
describe the relationship between rate and concentration using I-C reaction
- directly proportional
- concentration increases increases hydrogen peroxide particles number of collisions
- ensure temp is constant