rate of reaction Flashcards

1
Q

what is collision theory

A

chemical reaction occur when reactants collide successfully for a collision to be successful, the reactant particles must collide with correct orientation which is greater than or equal too activation energy of reactant

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2
Q

what effects collision theory

A
  • temperature
  • pressure
  • surface area
  • addition of a catalyst
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3
Q

how does increasing temperature affect collision theory

A

increases the rate of reaction due to more kinetic energy at higher temperatures

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4
Q

how does increasing concentration and pressure affect collision theory

A

increasing concentration/ pressure increases rate of reaction. this is because there is an increase of reactant particles in the same volume therefore larger chance of collisions

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5
Q

how does increasing surface area affect collision theory

A

increases rate of reactions as it exposes more particles to the surface which allows them to have a higher chance of collisions

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6
Q

how does the addition of a catalyst affect collision theory

A

increases rate of reaction

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7
Q

the equation for calculating rate of reaction

A

rate = change in concentration / time

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8
Q

what does the boltzmann energy distribution curve

A

at a given temperature, not all the particles in a sample have the same energy.

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9
Q

what effect does the catalyst have on a reaction

A

changes the activation energy

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10
Q

define a homogeneous catalyst

A

same physical state as the reactants. takes active part in the reaction and are then regenerated as the reaction proceeds

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11
Q

define a heterogenous catalyst

A

different physical state as reactants. provides a surface for reactant particles to absorb to, which holds them in place to react. the product then desorb from the surface

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12
Q

how to measure rate of reaction by gas collection method

A

rate of reaction = volume/time

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13
Q

what is the iodine clock used for

A

to compare reactions under different conditions. it involves setting up reactions with known concentration and time is recorded

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14
Q

describe the method of an iodine clock

A
  1. add these to a conical flask
    - KI
    - sodium thiosulfate
    - starch solution
  2. add 5cm of hydrogen peroxide to the mixture and start stopwatch
  3. stop timer when it turns blue black
  4. repeat using different conc of hydrogen peroxide
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15
Q

describe the relationship between rate and concentration using I-C reaction

A
  • directly proportional
  • concentration increases increases hydrogen peroxide particles number of collisions
  • ensure temp is constant
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