Random Flashcards
IR SPEC
Bond
Frequency
Intensity
C=O 1680-1735 strong
C=C 1680-1620 variable
CtripleC 2260-2100 variable
CtripleN 2260-2220 variable
C-H 3300-2700 variable
N-H 3150-2500 moderate
O-H 3650-3200 broad
Skeptic
Person inclined to question or doubt all accepted positions
Critic
Expressing unfavorable opinion of something
Indubitable
Cannot be doubted, unquestionable
Amide
o=CNH2
Imine
C=N
Object placed in liquid will displace
an equal mass of fluid ( if it floats) and an equal volume (if it sinks)
Heat Curve
Since the chart has areas where temp is changing and not changing we need two separate equations. In places on the chart where temp is changing we use q = mcdT (since dT would be non-zero). But if we use the same equation at a phase change point (eg at 0 C where ice melts or vice versa) then dT = 0 and it would indicate that no heat is being transferred. But in order to melt ice heat NEEDS to be transferred to break bonds. It just so happens that they dont change temperature at that phase change. So at those points we use q = mL (or as I like to call it, q = nH since n = moles and H = enthalpy since those are the units you need).
Isothermal
no change in temp
isobaric
no change in pressure
isovolumetric
no change in volume
adiabatic
no heat in or out of system
VAT
Vf= Vo + at
VAX
Vf^2= Vo^2 + 2a delta (x)
TAX
delta x= vot + 1/2 at^2
Newton SI Unit
kg meters/ seconds squared
Electric Field SI Unit
Newton/ Coulomb
The Limbic System
Set of structures residing below the cerebrum on either side of the thalamus
Parts of the Limbic System
Amygdala (small round structure, signals cortex about stimuli related to attention and emotion Fear - Emotion through interpretation of facial expressions). 2 Thalamus (preliminary sensory processing station and routes info to the cortex and other areas of the brain). Hypothalamus (synthesizes and releases NT, homeostatic and modulates emotion) 4. Hippocampus (LT memory)
Formation of Memory Explicit Vs Implicit
Explicit- memory about emotion. Implicit- Emotional Memory
Retrieval of Memory Explicit Vs Implicit
Explicit Consious memory of event Implicit- Expression of emotional responses.
Prefrontal Cortex
Anterior portion of frontal lobe with planning intricate cognitive functions, expressing personality and making decisions
Stress
Challenging events, physical , emotional cognitive and behavioral.
Cognitive appraisal, primary and secondary appraisal
Cognitive appraisal is the subjective evaluation of a situation that induces stress. pirmary appraisal = initial evaluation of environment and associated threat. Can be identified as irrelevant, benign, or stressful. If it is a threat then secondary appraisal begins in which we assess if we can cope with the stress
Types of stressors
Environment, workplace, social etc. Distressors are unpleasent stressors and Eustress is Positive conditions such as graduating or a high MCAT score
Physiological response to stressors
Sympathetic Nervous System. General Adaptation Syndrome is a sequence of physiological resonses in 3 distinct stages (Alarm [initial rxn to a stressor and activation of SNS- could involve hypothalamus to stimulate pituitary to secrete ACTH which acts on adrenal glands- make cortisol. Hypothalamus can also stimulate the adrenal medulla to release epi and norepi to activate SNS]. 2 Resistance- involves continuous release of hormones, SNS engaged to fight teh stressor. 3. Exhaustion- Cant maintain elevated response from SNS))
Coping with stress strategies
1 Problem- Focused, working to overcome stressor, making a plan. 2 Emotionally focused- changing feelings about a stressor. Coping can be adaptive (reach out for support) or maladapative ( drugs and alchol).
Disaccharides
form as a result of glycosidic bonding between two monosaccharide subunits; polysaccharides form by repeated monosaccharide or polysaccharide glycosidic bonding
Common disaccharides
Sucrose ( glucose a 1.2 fructose) Lactose (galactose B 1-4 glucose) Maltose (glucose a 14 glucose)
Monosaccharides
single carbohydrate units with glucose as the most commonly observed monomer. they can undergo three main reactions. oxidation reduction, esterification, and glycoside formation.
Aldoses can be oxidized to ___ and reduced to ___
oxidized to aldonic acids and reduced to alditols
Sugars that can be oxidized are ___ themselves, and can be detected by reacting with ___ or ___ reagents
sugars that can be oxidized are reducing agents themselves and can be detected by reacting with tollens or benedicts reagents
LiAlH4 is a
reducing agent
By reducing an aldose you get an
alditol (alcohol)
Planar hybridization
sp2
Conjugation
Conjugated double bonds in a molecule, mean that the single and double bonds alternate. These enables the electrons to be delocalised over the whole system and so be shared by many atoms. This means that the delocalised electrons may move around the whole system.
Lac operon
Is inducible because it is always off but we can induce it to turn on. Inducer binds to the repressor to free the operator region
Trp operon
Is repressible because it is always on. We are only going to supress it if we have enough of the food source and we dont need it. In the presence of co-repressor (tryptophan) it binds to the repressor to bind the operator
ACTH is released by
anterior pituitary
Cortisol release
adrenal cortex
Franz Gall
Phenology. If a particular trait was well developed the part of the brain responsible for that trait would expand
Franz Gall
Behavior, intellect and personality linked to brain anatomy
Pierre Flourens
Functions of major sections of brains. By extirpation. Parts of the brain are surgically removed and behavior consequences were observed (ablation) conclusion : each area has specific functions
Functionalism
William James and John Dewey. James= how the brain adapts to environment. Dewey = organism as a whole as it is functioned to adapt to the environment. Functionalism (psychology- how mental processes help individuals adapt to their environment)
Paul Broca
Linked specific deficits to specific brain lesions. Broca’s area- a major language center
Helmholtz
Measured speed of a nerve impsulse. Transition of psychology to neuroscience
Sir Charles Sherrington
Inferred the existence of synapses
Phrenology
Well developed traits led to expansion of specific part of the brain (proven incorrect)