quiz 5 prep Flashcards

1
Q

simple lipids are glycerides also called ____

A

acylglycerols

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2
Q

glycerides are made up of ____

A

esters of glycerol and 1, 2, or 3 fatty acids

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3
Q

_____ are the main component of fats and oils

A

glycerides

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4
Q

saponification is

A

hydrolysis of triglycerides with alkali (NaOH, KOH)

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5
Q

saponification forms ____+_____

A

glycerin + salts of fatty acids

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6
Q

salts of fatty acids =

A

soap

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7
Q

____ soap is made from tallow/lard

A

lye

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8
Q

saponification number is equivalent to

A

the amount of alkali needed to completely saponify 100g of fat/oil

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9
Q

an increase in the saponification number = a decrease in ____

A

the average fatty length

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10
Q

Iodination: ____ fatty acids readily bond to iodine with ___ iodine atoms at each end

A

unsaturated; 2

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11
Q

Hydrogenation is ___

A

adding H to unsaturated fatty acids

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12
Q

hydrogenation converts ___ to ___ and removes ____

A

double bonds to single bonds; “kinks”

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13
Q

What does hydrogenation do to vegetable oils?

A

it solidifies them

think margarine/shortening

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14
Q

hydrogenation can convert ___ double bonds to ___

A

cis; trans

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15
Q

are there health concerns associated with chemically hydrogenated “trans fat”

A

yes; increased serum cholesterol; heart disease, diabetes, etc.

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16
Q

oxidation (“____”) is the formation of ____

A

Rancidity; free radicals

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17
Q

what do free radicals break?

A

C-C bonds of fatty acids

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18
Q

oxidation causes a disagreeable _____ such as in ____

A

odor/flavor; blue cheese

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19
Q

oxidation helps the addition of antioxidants such as

A

Se, Vit E, Vit C, betacarotene, ethoxyquin, BHA, BHT

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20
Q

another simple wax is ___ which has minor importance in nutrition, a low digestibility, and greater commercial value

A

waxes

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21
Q

___+___+___= compound lipids

A

fatty acids
alcohol
nonlipid

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22
Q

what are phospholipids?

A
  • white waxy solids that turn brown when exposed to air

* constituents of biological membranes

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23
Q

what composes a phospholipid?

A
  1. glycerol (or other alcohol) backbone
  2. at least one fatty acid
  3. phosphoric acid
  4. nitrogenous base (usually choline, ethanol amine, serine)
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24
Q

What is amphipathic organization?

A

It contains both hydrophilic and hydrophobic portions in the same molecule

  • hydrophilic: water soluble such as phosphoric acid, amino acid groups
  • hydrophobic: lipid soluble such as fatty acid tails
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25
lecithin (phosphatidylcholine) = ___+___+___+___
glycerol + 2fatty acids + phosphoric acid + choline
26
Lecithin in foods acts as
1, natural emulsifier 2. carrier for micronutrients 3. use in cosmetics
27
cephalin (phoshatidylethanolamine) is
white matter of brain and spinal cord | similar to lecithin, with ethanol amine instead of choline
28
sphingomyelin is
a component of nervous tissue (myelin sheath) | uses sphingosine instead of glycerol
29
glycolipids = ___+___+___
glycerol 2 fatty acids sugar residue
30
up to 60% of the lipid in forages can be ____ (in chloroplasts), a glycolipid
galactolipid
31
glycolipids in animals compose:
1. myelin sheath (cerebrosides) | 2. brain tissue (gangliosides)
32
glycolipids determine____
blood type
33
glycolipids determine blood type from ___
CHO on surface of red blood cells
34
lipoproteins transport ____
molecules for lipids in blod (fatty acids and cholesterol)
35
lipoproteins are synthesized in ___
the small intestine during absorption (chylomicron)
36
chylomicrons are repackaged in ___
the liver
37
LDL stands for _____. Transports to ___ and is considered ___ cholesterol
Low Density Lipoprotein peripheral cells bad cholesterol
38
HDL stands for ____. Transports to _____ and is considered ____ cholesterol
High Density Lipoprotein back to the liver good cholesterol
39
Derived lipids include:
1. sterols 2. steroid hormones 3. ProVitamin D 4. Bile acids 5. Prostaglandins
40
____ is the parent molecule of sterols
cholesterol
41
Steroid hormones include:
1. testosterone, estrogen, progesterone 2. cortisol (stress hormone) 3. Aldosterone (kidneys)
42
bile acids conjugated to glycine and taurine are
glycocholic acid and taurocholic acid
43
prostaglandins are derivatives of
arachidonic acid
44
Prostaglandins stimulate ____ and contribute to
smooth muscle contractions; inflammatory response, regulation of blood pressure, fever, reproduction (ovulation, menstruations, parturition)
45
NSAIDS are _____ such as
non-steroidal anti-inflammatory drugs; aspirin, ibuprofen, naproxen
46
How do NSAIDS work?
they block synthesis of prostaglandins from arachidonic acid which inhibits cyclooxygenase (COX) enzymes
47
What lipolytic enzymes come from the mouth?
NONE
48
Presence of ____ (distension) in stomach causes the release of the hormone ___ by ____
food; Gastrin: pylorus
49
Gastrin stimulates overall gastric secretion:
Mucous, HCl, Pepsin, GASTRIC LIPASE
50
Gastric Lipase comes from ____ and hydrolyzes ___ into ____
chief cells; triglycerides into monoglyceride and 2 free fatty acids
51
gastric lipase in the adult stomach is ____by the low pH but is ____ in the small intestine
denatured; reactivated
52
gastric lipase plays a bigger role in ____
milk fed animals
53
____ from the crypts of lieberkuhn, is triggered by the presence of ____ and stimulates ____ to release___
secretin; gastric acid (HCl); pancreas; bicarbonate buffers
54
____ from the crypts of lieberkuhn is triggered by ____ and stimulates___ to release____
Cholecystokinin; the presence of lipid/peptides; pancreas; digestive enzymes
55
_____ is similar but more potent than gastric lipase
pancreatic lipase
56
pancreatic lipase hydrolyzes ___ to ____+____
triglycerides; monoglyceride and 2 free fatty acids
57
_____ removes fatty acid esterified to cholesterol
cholesterol esterase
58
_____ hydrolyzes lecithin and other phospholipids
phospholipase
59
CCK stimulates ____ for bile release into duodenum
contraction of the gall bladder
60
____ comes from the liver and gall bladder
bile
61
Bile aids in the emulsification of lipids, acts as _____ and helps the formation of ____ for increased surface area for lipase action
a detergent; micelles
62
Absorption of mixed micelles contents uses ____ into the enterocyte
passive diffusion
63
Mixed micelle contents undergo ___ into triglycerides inside the enterocyte and ____(lipoproteins) are formed in the endoplasmic reticulum
re-esterification; chylomicrons
64
Chylomicrons are expelled from the enterocyte via ___ into ____ in mammals and ____ in birds.
exocytosis; lacteal; blood capillaries
65
chylomicron are transported in lymph to the liver and other peripheral tissues for ____ into other lipoproteins
repackaging