Quiz 11 Notes (Exam 4) Flashcards

1
Q

What is the Nernst Equation used for?

A

It is used for non-standard condition

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2
Q

What is the Nernst equation?

A

*Ecell=Ecell(standard) - 0.0592v divided by n times log Q

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3
Q

What is being described?:
Cell reaction must be driven by imposing by a cell voltage

A

Electrolytes (Electrolytic cell)

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4
Q

What two things make up a nucleus?

A

Protons and Neutrons

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5
Q

What defines an element?

A

Protons

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6
Q

What does A represent in nuclear structure notation?

A

Mass number

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7
Q

What does mass number consist of?

A

Number of protons

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8
Q

What does Z represent in nuclear structure notation?

A

Atomic number

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9
Q

What does the atomic number consist of?

A

Sum of protons and neutrons (number can differ, creating isotopes)

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10
Q

What is being described?:
High energy helium nuclei?

A

Alpha particle

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11
Q

What is being described?:
High energy electron

A

Beta particle

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12
Q

What is being described?:
Same mass as electrons but postive charge

A

Positron

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13
Q

What is being described?:
hydrogen nuclei

A

Proton

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14
Q

What is being described?:
very high energy EM radiation

A

Gamma ray

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15
Q

Which type of decay has a parent and daughter nuclide?

A

Alpha decay

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16
Q

Which type of decay is the conversion of a neutron to a proton?

A

Beta decay

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17
Q

Which emission is being described?:
The nuclide forms in an excited state; then decays to ground state

A

Gamma Emission

18
Q

Which emission is being described?:
Proton is converted into a neutron

A

Positron emission

19
Q

What is being described?:
Internal process where inner electrons combines with proton; outer electrons fill vacancy left; energy emitted (x-ray)

A

Electron capture

20
Q

What is a fundamental force of physics?
- In all nucleons (protons and neutrons)
- Attracted to each other
- Acts over very small distances

A

Strong force

21
Q

What is a balance between the coloumbic (charge) repulsive force and attractive strong force?

A

Stability

22
Q

What does n over z equal for elements 1-20?

A

1

23
Q

What does n over z equal for elements 20-40?

A

1.25

24
Q

What does n over z equal for elements 40-80?

A

1.5

25
Q

What happens for elements that are greater than 83?

A

There is no stable nuclei

26
Q

What happens when n over z is too high?

A

Beta decay will occur

27
Q

What happens when n over z is too low?

A

Positron emission AND/OR electron capture will occur

28
Q

What happens when there is heavy nuclei?

A

Alpha decay occurs (only one that reduces mass)

29
Q

What is the nuclear equation for alpha particle?

A

Write it out

30
Q

What is the nuclear equation for beta particle?

A

Write it out

31
Q

What is the nuclear equation for positron?

A

Write it out

32
Q

What is the nuclear equation for proton?

A

Write it out

33
Q

What is the nuclear equation for neutron?

A

Write it out

34
Q

What is the delta G equation?

A

Delta G= -n(F) Ecell

35
Q

What does the constant F equal?

A

96485

36
Q

What is the first order integrated rate law?

A

ln (Nt/N0)= -kt

37
Q

What is the 1st order half life equation?

A

t1/2= 0.693/k

38
Q

What is the Ecell equation?

A

Ecell(standard)= -(0.0592/n) log Q

39
Q

What is the Ecell equation (when you have t)?

A

Ecell(standard)= -(RT/nF) lnQ

40
Q

What is included in the transition metal group?

A

Halides, hydroxides, carbonates, oxides