Properties of gases - Ch10 Flashcards
Diffusion
Spreading out of particles from an area of high concentration to an area of low concentration.
Temperature
C° (+273) –> K
Use: thermometre
Pressure
KPa (x1000) –> Pa
Use: Barometer
Volume
m³ (x10⁻⁶) –> cm³
Boyle’s law
At constant temperature, the volume of a fixed mass of gas is inversely proportional to its pressure.
Charle’s law
At constant pressure, the volume of a fixed mass of gas is directly proportional to its temperature measured on Kelvin Scale.
Combined gas law (Boyle’s + Charles’)
P1V1 / T1 = P2V2 / T2
Gay-Lussac
Gases react in the ratio of small whole numbers at constant temperature and pressure.
Avogadro’s law
Equal volumes of gases contain equal numbers of molecules under the same conditions of temperature and pressure.
Molar volume
- STP = 22.4 L
- Room temp = 24 L
Volatile
Low boiling point
Experiment
- Measure mass of flask with Al foil + rubber band
- Leave 8 minutes in boiling water bath + hot plate + pinhole in foil (to equalise pressure) until fully vaporises
- Take out, let it cool, dry + reweigh + substruct from initial volume.
PV=nRT
- P = Pa (barometer)
- V = m³
- n = ? (mass)
- R = 8.31 (always given)
- T = K (thermometer)
Brownian motion
Random movement of tiny particles in a liquid or a gas.
Kinetic theory of gases assumptions:
- All collisions are perfectly elastic
- There are no attractive or repulsive forces between molecules of a gas
- Their volume is negligible compared to the space they occupy
Kinetic theory of gases limitations:
- There are attractive and repulsive forces between molecules of a gas
- Their volume is not negligible under high pressure
Ideal gas:
One that follows all the assumptions on the kinetic theory of gases.
Gas closest to ideal
H2 (Hydrogen GAS)
Closest noble gas
He (Helium), because it is the smallest noble gas
Real gas
Differs from ideal gases because:
- Forces of attraction + repulsion do exist between the molecules
- Volume of the molecules is not negligible
When are real gases closest to be ideal?
High temperature, low pressure.