Organic chemistry - Ch21 Flashcards

1
Q

What is organic chemistry?

A

The study of compounds of carbon.

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2
Q

What is a hydrocarbon?

A

A compound that contains carbon and hydrogen only.

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3
Q

Sources of hydrocarbons?

A

Coal, natural gas (methane), petroleum (crude oil).

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4
Q

What are fossil fuels

A

Fuels that were formed from the remains of plants and animals that lived millions of years ago.

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5
Q

What are the three types of hydrocarbons?

A

Alkanes, alkenes and alkynes.

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6
Q

What are alkanes?

A

Family of hydrocarbons in which all the atoms are linked by single bonds. They are saturated compounds.

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7
Q

What is a saturated compound?

A

One in which there are only single bonds between the atoms in the molecule / compound that contains carbon carbon single bonds only.

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8
Q

What is a homologous series?

A

A series of compunds of similar chemical properties, showing gradations in physical properties, having a general formula for its members, each member having a similar methos of preparation, each member differing from the previous member by a (CH2) unit.

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9
Q

What are structural isomers?

A

Compounds with the same molecular formula but different structural formula.

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10
Q

What are alkenes?

A

Family of hydrocarbons that contain one carbon-carbon double bond between two of the carbon atoms in the molecule. They are unsaturated.

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11
Q

What is an unsaturated compound?

A

One that contains one or more double or triple bonds between the atoms in the molecule.

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12
Q

What are alkynes?

A

Family group of carbohydrates that contain a carbon-carbon triple bond. They are highly unsaturated.

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13
Q

What is an aliphatic compound?

A

An organic compound that consists of open chains of carbon atoms and closed chain compounds (rings) that resemble them in chemical properties.

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14
Q

What is an aromatic compound?

A

compound that contains a benzene ring structure in its molecules.

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15
Q

From where is crude oil pumped?

A

From under the ground / under the sea.

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16
Q

Characteristics of curde oil?

A

Doesn’t burn very easily, thick black liquid, unpleasant smell.

17
Q

What is fractional distillation?

A

A process that is used to separate crude oil into a number of useful parts.

18
Q

Why is methane a good fuel?

A

Clean, pelntifull, cheap and easy to get into our homes.

19
Q

What are mercaptants?

A

Sulfur compounds added to give gases an unpleasant smell to warn of gas leaks.

20
Q

What is petrol used for?

A

Motor fuel (in cars).

21
Q

What is naphtha used for?

A

Petrochemical industry.

22
Q

What is kerosene/paraffin oil used for?

A

Domestic heating oil and fuel for aircraft.

23
Q

What is diesel oil or gas oil used for?

A

Fuel in trucks, buses, trains.

24
Q

What is lubricating oil used for?

A

To reduce the wear-and-tear in engines.

25
What is bitumen used for?
Roads, roofing.
26
What is fuel oil used for?
Fuel in ships, power stations, heating plants.
27
What is knocking?
The early explosion.
28
What is auto ignition?
The early explosion of the petro-air mixture before the normal ignition of the mixture by a spark takes place.
29
What is the octane number of a fuel?
Measure of the tendency of the fuel to resist knocking.
30
What factors affect octane number?
1. Length of chain: the shorter the alkane chain, the higher the octane number. 2. Degree of branching: the more branched the chain, the higher the octane number. 3. Straight-chain/cyclic structure: cyclic compounds have a highest octane number than straight-chain compounds.
31
What are 4 ways to increase the octane number?
1. Isomerisation 2. Catalytic cracking 3. Dehydrocyclisation 4. Adding oxygenates
32
What is isomerisation?
Changing straight-chain alkanes into their isomers.
33
What is catalytic cracking?
The breaking down of long-chain hydrocarbon molecules by the action of heat and catalysts into short-chain molecules for which there is greater demand.
34
What is dehydrocyclisation?
Use of catalysts to form ring compounds. (Ring formation and removal of hydrogens).c
35
What is heat of reaction?
The heat change when the numbers of moles of reactants indicated in the balanced equation for the reaction react completely.
36
What is heat of combustion?
The heat change when one mole of the substance is completely burned in excess oxygen.
37
What is heat of neutralisation?
The heat change when one mole of H+ ions from an acid reacts with one mole of OH- ions from a base.
38
What is heat of formation?
The heat change that takes place when one mole of a compound in its standard state is formed from its elements in their standard states.