Process - CPI Flashcards
Addition of alkyl radical with side chain final product
Alkylation
Example of alkylation applications
Petroleum
Organic chemicals
Creation of amine group by addition of ammonia
Amination by ammonolysis
Applications of ammonolysis
Dyestuffs
Synthetic fibers
Organic chemicals
Creation of amine group by adding hydrogen gas
Amination by reduction
Applications of amination by reduction
Dyestuffs
Organic chemical
Creation of amine group and oxidation
Ammonoxidation
Application of ammonoxidation
Plastics
Synthetic fibers
Process of heating limestone to produce lime
Calcination
Application of calcination
Cement
Creation of carbonyl compounds
Carbonylation
Creation of carboxylate salts
Carboxylation
Combination of two organic molecules
Condensation
Application of condensation
Synthetic perfumes
Separation of long C-C chains into smaller chains
Cracking or pyrolysis
What process is used in destructive distillation of coal and petroleum
Cracking or pyrolysis
Production of cyanide
Cyanidation or cyanation
Creation of cyclic compounds from C-C chains
Cyclization
Where is cyclization applied?
Petroleum
Removable of water
Dehydration
Removal of hydrogen
Dehydrogenation
Where is dehydrogenation usually applied?
Synthetic rubbers
Occurs between diazonium ions and the phenolic tyrosine, resulting in three new typical peaks in the SERS spectrum of thr azo dye
Diazotization and coupling
When a substance is simultaneously reduced and oxidized
Disproportionation
Other term for double decomposition (switching of ion pairs in inorganix chemicals)
Metathesis
Adding acid to alcohol triggers
Esterification
Application of esterification
Oils and fats
Soaps
Addition of halogen to org compound performed with/without light
Halogenation
Addition of water
Hydration
Production of aldehydes from alkenes
Hydroformylation
Other term for hydroformylation
Oxo synthesis
Addition of hydrogen
Hydrogenation
Applications of hydrogenation
Fats and waxes
Coal hydrogenation
Petroleum
Cleavage of bonds by the addition of water
Hydrolysis
Oxidation of CH into COH
Hydroxylation
Application of hydroxylation
Detergent
Transformation of molecules into a different isomer
Isomerization
Where is isomerization applied?
Petroleum
Introduction of nitro group into a organic compound
Nitration
Application of nitration
Explosives
Dyestuffs
Conversion of monomers to macromolecular complexes thriugh a finite defree of polymerization
Oligomerization
Applications of polymerization
Petroleum
Plastics
Elastomers
Synthetic fibers
Production of benzenesulfonic acid by adding SO3 and H2SO4
Sulfonation
Application of sulfonation
Dyestuff
Conversion of carbonyl group to thiocarbonyl
Thionation
Manufacture of paper from pulp employing the Foudrinier machine
Kraft Processes
Method of recovering hydrogen from water gas; carbon dioxide is reacted with steam at 500 C in the presence of catalyst to form co and h2
Bosch Process
Recovering copper from its sulfide ores by leaching with cupric and sodium or calcium chloride solutuon and electrolyzing, product is cupric chloride
Hoepener Process
Copper or iron sulfides fused and blown with air to burn out the sulfur content
Holloway process
Formation a rust resistant coating on iron, base metal by oxidation with superheated steam
Barff process
Process for reduction of lead ores, small charge is roasted slowly at a low T, lead being collected outside the furnace by means of heat
Carinthian process
Method of recovering gold and silver from their ores into a soluble form by treatments with cyanides
Cyanidation process
Rubber reclaiming process in which vulcanized scraps are introduced into a mixer (Banbury) where im the presence of air it is worked under pressure and at high T for a very short time
Babbyry Process
Sulfonation and extraction process in the manufacture of phenol
Dennis Bull Process
Soda ash manufacture
Solvay Process
Production of ammonia by direct combination of N2 and H2 at 600 under 200-300 atm in presence of catalyst
Haber Bosch Process
Process of recovering sulfur from the buried porous cap rock of a salt dome and delivering it above ground as a product of suitable purity and condition for use
Frasch Process
Extraction of aluminum from bauxite
Hall’s process
Catalysts used in manufacture of sulfuric acid by chamber and contact processes
Chamber: oxides of nitrogen
Contact: V2O5 (vanadium oxide) on a porous carrier
In contact process SO3 is absorbed in 97% H2SO4 because
water forms an acid mist which is difficult to absorb
Contact process yields __ concentration than chamber process
Higher
Producer gas contains mainly
CO, CO2, H2 and N2
Oxygen is produced by fraction of air using
both Linde’s Process and Claude’s Process
Raw materials for Solvay Process
Salt, limestone, ammonia, coke oven gas
Economics of the Solvay Process depends upon the efficiency of
Ammonia recovery and size of plant
Cement contains
CaO, SiO2, Al2O3
Permanent hardness of water is due to the presence of magnesium and calcium
sulphides and chlorides
Widely used method for conditioning of boiler feed wider
Hot-lime soda process
Hydrazine is widely used in
as rocket fuel
Trinitro-toluene is
an explosive
A mixture of glycerides of fatty acids
Oil
Mixture of esters of polyhydric alcohols except glycerin
wax
Unsaturated oils compared to saturated oils have
lower melting point and higher reactivity to oxygen
Rancidity of oil can be reduced by
Hydrogenation
Solvent used for extraction of oil
methyl ethyl ketone
Catalyst used in hydrogenation of oil
Nickel
Metallic soap is made of
aluminum and calcium salt of fatty acids
Fat splitting catalyst
ZnO
Free alkali in toilet soap is _____ that in laundry soap
less than
Builders are added in soap to
boost cleaning power
Biodegradable detergents
can easily be oxidized
Alkyl benzene sulfonate is
a detergent
Yellow glycerin can be made into white usin
activated carbon
How are essential oils usually obtained
steam distillation
Why are plasticizers added to paints
to give elasticity and prevent cracking of the film
Which oil is preferred in paint manufacturing
Drying oil
What is the function of a thinner in a paint
Suspend pigments and dissolve film-forming materials
Enamels
give good glossy finish
Why is SO2 bubbled through hot sugar-cane juice
act as an acidifying agent
substance that increases strength of tires
carbon black
common hydrocarbon gas liquids
butane and propane
refers to gases produced during oil production
associated gas
gases separated during oil refining
refinery gas
Catalyzed reaction of carbon monoxide and hydrogen to form hydrocarbons
Fischer-Tropsch process
Fischer-Tropsch synthesis feed quality guidelines
< 1 ppm sulfur, <1% aromatics
ideal catalyst for light components production in FT (gasoline)
iron
ideal catalyst for heavy component production in FT (diesel, waxes)
nickel
range of carbon lengths for LPG gas
C1 to C4
Range of naphtha carbon lengths
C5 to C12
Range of kerosene carbon chain lengths
C6 to C12
Range of carbon chain lengths for diesel/gasoline
C12-C18
Range of carbon chain lengths for lubricating oil
C16-C22
Range of carbon chain lengths for residue/asphalt/paraffin waxes
> C20
Process of producing 1,3 propanediol using a bioreactor (E. coli)
DuPont process
Chemical which is the precursor of nylon-6
Caprolactam
major source of cheap natural gas
Middle East