Principles Flashcards
Mass number
Protons + neutrons
Atomic number
Number of protons (as well as electrons)
Relative atomic mass
Isotopes
Percentages of each mass no
Relative formula mass
Mr of each part added
Mole
6 x10 ^23 (Avogadro no)
Calc for mol
Mass= Mr x mol
Volume calc
Vol (dm3) = amount mol x 24
Vol (cm3) = amount mol x 24000
Empirical formula
Simplest whole no ratio of atoms of each element in a compound
Molecular formula
Exact number of atoms present on the formula of a compound
Need Mr and empirical formula
Find Ef mass and divide into Mr
Then times all parts by that no
Conc equation
Mol= vol (cm3) x conc (mol/dm3)
——————————–
1000
Diffusion
- 3 experiments
Bromine gas
Potassium 7 manganate
Hydrochloric acid and ammonia
Percentage yield
Yield obtained
—————– X 100
Theoretical yield.
Yield= amount of product obtained
Ionic compounds key words
Loss or gain of electrons
Metals + non metals
Ionic lattice
Electrostatic force of attraction between oppositely charged ions (ionic bond)
Giant ionic
Covalent substances
Two non metals
Shared pair of electrons
Valence electrons
Simple molecular
Diatomic elements
Low mp and bp
Forces of attraction are weak in comp to electrostatic forces
Often gases
When they change state the covalent bonds not usually broken (just the forces of attraction between the molecules)
Methane
CH4
Ammonia
NH3
Ethane
C2H6
Ethene
C2H4
Giant covalent
Diamond, graphite, silicon dioxide
V high mp and bp
Diamond
Each carbon with 4 other Three dimensional structure formed All 4 Valence electrons used Covalent bonds are strong V high mp and bp Very hard and abrasive Doesn't conduct electricity Cutting tools/ jewelry
Graphite
Three bonds for each carbon One free A layered structure Covalent bonds strong Forces of attraction between layers weak V high mp Soft and slippery Conducts electricity Lubricant Electrodes for electrolysis
Metallic crystals
Giant 3D lattice structure
Positive IONS arranged in a regular pattern in a sea of electrons
Valence electrons are detached from the atoms and are delocalised
Bond between positive ions and delocalised electrons is known as a metallic bond
High mp and bp
Good electricity conductors
Malleable and ductile
Electrolysis def
Decomposition of a substance via the passing of an electrical current through it
Molten electrolysis rules
Cathode - metal - negative electrode
Anode - nmetal - positive
Molten sodium chloride
Cathode - sodium
Anode- chlorine
Molten calc
Lead
Bromine
At cathode:
Pb2+ + 2e- > Pb
At anode:
2Br- > Br2 + 2e-
Aqueous electrolysis
At neg = hydrogen or metal
At pos = oxygen or halogen
Hydrogen formed unless metal is below in reactivity series
Equations of hydrogen in aqueous (electrolysis)
In neutral solutions of salts
2H2O + 2e- > H2 + 2OH-
In acidic conditions
2H+ + 2e- > H2
Oxygen formed in aqueous (electrolysis)
2H2O > 2H2 + O2
4OH- > O2 + 2H2O + 4e-
Electrolysis calc
Quantity (C) = current (A) x Time (s)
96500C = 1Faraday = 1mol electrons