Chemistry In Society (b) Flashcards
Refining of crude oil through…
Fractional distillation
Fractional distillation carried out in a..
Fractionating column
Order w highest bp first
Big. Bitumen Farty. Fuel oil Daddy. Diesel Kan. Kerosene Go. Gasoline (petrol) Red. Refinery gases
Crude oil def
A thick, sticky, black liquid that is found under the ground and under the sea
A mixture of hydrocarbons
Use of refinery gases
Bottled gas for camping
Use of gasoline
Petrol for cars
Use of kerosene
Fuel for aeroplanes, ‘oil’ for central heating
Paraffin for small heaters and lamps
Use of diesel oil
Diesel fuel for buses, lorries, trains and cars
Use of fuel oil
Fuel for ships and for industrial heating
Use of bitumen
Road surfaces and covering flat roofs of building
Crude oil is split into
Fractions
A fraction is
A mixture of hydrocarbons with v similar boiling points
Process of refining crude oil
Crude oil heated to convert into a vapour- vapour then fed into the bottom of the fractioning column
Hydrocarbons w v high bps immediately turn to liquids and are tapped off at bottom
At temp 400c
Hydrocarbons that have lower bps rise and remain as gases until cooling and condensing
Bubble caps prevent backward movement
They are tapped off separately
Refinery gases remain as gases so come out the top (around 40c)
Change in boiling point
Decreases as you go up column
Change in viscosity
Decreases as you up column
Change in colour
Decreases in darkness as you rise up column
Change in number of carbon atoms in molecule (length of carbon chain)
Decreases as you rise up column
Short chain
Long chain hydrocarbons
What is cracking?
A method of converting long chain hydrocarbons in the higher bp fractions into shorter chain hydrocarbons in order to make gasoline and so make more petrol for cars
How does cracking work?
Long chain hydrocarbon molecules are passed over a catalyst (silica or aluminium oxide) and heated to about 600-700*c. Long chain hydrocarbons break down into short chain alkane molecules and at least one alkene molecule
C10H22 cracking goes to…
C8H18 + C2H4
Octane. And Ethene
Octane used to make petrol
Ethene for polyethene
Burning fuels in cars
Incomplete combustion of alkanes produce carbon monoxide
Same in petrol when burnt as some is not burnt due to lack of oxygen
Poisonous and dangerous
Dangers of burning fuel
Carbon monoxide- poisonous to humans as reduces capacity of blood to carry oxygen
Temp in a car engine is high enough for nitrogen and oxygen from the air to react to form oxides of nitrogen. These oxides are also passed out and when they reach the atmosphere can dissolve in water in the air to form acid rain
Catalytic converters- what?
Placed in exhaust system of a car
Attempt to convert as much carbon monoxide into carbon dioxide and also concert nitrogen oxides into nitrogen and oxygen